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H10401 Aldrich

Hexamethyleneimine

99%

Synonym: 1-Azacycloheptane, Azepane, HMI, Hexahydro-1H-azepine, Homopiperidine, Perhydroazepine

  • CAS Number 111-49-9

  • Empirical Formula (Hill Notation) C6H13N

  • Molecular Weight 99.17

  •  Beilstein Registry Number 1084

  •  EC Number 203-875-9

  •  MDL number MFCD00006934

  •  PubChem Substance ID 24895424

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Properties

Related Categories Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Homopiperidines
vapor pressure   7.4 mmHg ( 21.1 °C)
InChI Key   ZSIQJIWKELUFRJ-UHFFFAOYSA-N
assay   99%
refractive index   n20/D 1.466(lit.)
bp   138 °C/749 mmHg(lit.)
density   0.88 g/mL at 25 °C(lit.)

Description

Packaging

25, 100, 500 mL in glass bottle

Application

Hexamethyleneimine (HMI) can be used in the preparation of:
• zeolitic catalysts such as MCM-22 and MCM-49
• SAPO-35, a molecular sieve
• various microporous aluminosilicates and titanosilicates
• organic-inorganic hybrid pervoskite


It can also been used in the total synthesis of various natural products and bioactive molecules such as (−)-balanol, indole estrogens, derivatives of daunorubicin and (+)-cetiedil.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 2493 8(3) / PGII
WGK Germany 
3
RTECS 
CM3150000
Flash Point(F) 
64.4 °F
Flash Point(C) 
18 °C

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Protocols & Articles
Peer-Reviewed Papers
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References

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