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N32407 Sigma-Aldrich

Bicyclo[2.2.1]hept-2-ene

99%

Synonym: 2-Norbornene, Norbornylene

  • CAS Number 498-66-8

  • Empirical Formula (Hill Notation) C7H10

  • Molecular Weight 94.15

  •  Beilstein/REAXYS Number 1098544

  •  EC Number 207-866-0

  •  MDL number MFCD00082304

  •  PubChem Substance ID 24897631

  •  NACRES NA.22

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Properties

Related Categories Alkenes, Building Blocks, Chemical Synthesis, Cyclic, Materials Science,
Quality Level   100
assay   99%
bp   96 °C (lit.)
mp   44-46 °C (lit.)
SMILES string   C1C[C@H]2C[C@@H]1C=C2
InChI   1S/C7H10/c1-2-7-4-3-6(1)5-7/h1-2,6-7H,3-5H2/t6-,7+
InChI key   JFNLZVQOOSMTJK-KNVOCYPGSA-N

Description

General description

The vinylic polymerization of bicyclo[2.2.1]hept-2-ene (norbornene) with Co(II) compounds and the metallocene [η5-(C5Me5)Co-η2-Cl]2, in chlorobenzene activated with methylaluminoxane (MAO) has been reported. Co(II) catalyzed polymerization of bicyclo[2.2.1]hept-2-ene in the presence of ethene has been reported.

Application

Bicyclo[2.2.1]hept-2-ene may be used in the preparation of cis,exo-2,3-diarylsubstituted bicyclo[2.2.1]heptanes or bicyclo [2.2.1] hept-2-enes.

Packaging

100, 500 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN1325 - class 4.1 - PG 2 - EHS - Flammable solids, organic, n.o.s., HI: all
WGK Germany 
WGK 1
RTECS 
RB7900000
Flash Point(F) 
17.6 °F - closed cup
Flash Point(C) 
-8 °C - closed cup

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

Related Products

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Product #

Description

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903698 1-Isopropyl-4-methyl-5-norbornene
903647 1-Heptyl-2-norbornene, ≥95%
903655 1-Cyclohexyl-2-norbornene

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