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T30805 Aldrich

Thioacetic acid

96%

Synonym: TAA, TMA, Thiacetic acid

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Properties

Related Categories Acids, Acids & Bases, Chemical Synthesis, Organic Acids, Synthetic Reagents More...
InChI Key   DUYAAUVXQSMXQP-UHFFFAOYSA-N
assay   96%
refractive index   n20/D 1.465(lit.)
bp   88-91.5 °C(lit.)
density   1.065 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

5, 100, 500 g in glass bottle

Application

Thioacetic acid (TAA) can undergo:
• Enantioselective addition to nitroalkenes to form chiral 1,2-aminothiol derivatives in the presence of a novel sulfinyl urea organocatalyst. This method has been successfully employed in the synthesis of antifungal drug, sulconazole.
• Asymmetric Michael addition reaction with chalcones in the presence of a bifunctional amine thiourea catalyst to form synthetically useful thioesters.
• Asymmetric 1,6-conjugate addition with para-quinone methides in the presence of a chiral phosphoric acid catalyst to form chiral sulfur-containing diphenylmethane-type compounds.
• Conjugate addition to methacrylamides with chiral trans-2,5-disubstituted pyrrolidine auxiliaries to form chiral β-mercaptocarboxylic acid derivatives.

Thioacetic acid is a reagent for introduction of the thiol group into organic molecules.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 2436 3 / PGII
WGK Germany 
3
RTECS 
AJ5600000
Flash Point(F) 
51.8 °F
Flash Point(C) 
11 °C

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Protocols & Articles

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MSMLS Online Plate Map

Metabolite descriptors included with the software download upon purchase of the product include: Name, Parent CID, molecular formula, molecular weight, CAS, ChEBI, HMDB ID, PubChem Compound and Subst...
Keywords: Mass spectrometry, Metabolites

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Peer-Reviewed Papers
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References

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