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08650 Supelco

Chlorobenzene

analytical standard

  • CAS Number 108-90-7

  • Empirical Formula (Hill Notation) C6H5Cl

  • Molecular Weight 112.56

  •  Beilstein/REAXYS Number 605632

  •  EC Number 203-628-5

  •  MDL number MFCD00000530

  •  PubChem Substance ID 329748622

  •  NACRES NA.24

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Properties

Related Categories A-C, Additional Standards, Analytical Standards, Analytical/Chromatography, Aromatics,
Quality Level   100
grade   analytical standard
vapor density   3.86 (vs air)
vapor pressure   11.8 mmHg ( 25 °C)
assay   ≥99.7% (GC)
autoignition temp.   1178 °F
shelf life   limited shelf life, expiry date on the label
expl. lim.   7.1 %
refractive index   n20/D 1.524 (lit.)
  n20/D 1.525
bp   132 °C (lit.)
mp   −45 °C (lit.)
density   1.106 g/mL at 25 °C (lit.)
Featured Industry   Cleaning Products
Cosmetics
Environmental
Food and Beverages
Personal Care
SMILES string   Clc1ccccc1
InChI   1S/C6H5Cl/c7-6-4-2-1-3-5-6/h1-5H
InChI key   MVPPADPHJFYWMZ-UHFFFAOYSA-N

Description

General description

Pure chlorobenzene is an aromatic organic compound most commonly used as a solvent and as a precursor in chemical syntheses. It is an intermediate in dyes and pesticide production and used in insect repellents, deodorants, and degreasers.

Application

Chlorobenzene may be used as an extraction solvent in the determination of chlorophenols in water samples and triazine herbicides in aqueous samples by chromatography techniques.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
RIDADR 
UN1134 - class 3 - PG 3 - Chlorobenzene
WGK Germany 
WGK 2
RTECS 
CZ0175000
Flash Point(F) 
80.6 °F
Flash Point(C) 
27 °C
Protocols & Articles

Articles

GC Analysis of Class 2 Residual Solvents on Equity®-1 after SPME using 85 μm Polyacrylate Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Class 2 Residual Solvents on Equity®-1 after SPME using 85 μm Polyacrylate Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Pharmaceutical, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Class 2 Residual Solvents on OVI-G43

From our library of Articles, Sigma-Aldrich presents GC Analysis of Class 2 Residual Solvents on OVI-G43
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Pharmaceutical, Size-exclusion chromatography

GC Analysis of Class 2 Residual Solvents on VOCOL® after SPME using 85 μm Polyacrylate Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Class 2 Residual Solvents on VOCOL® after SPME using 85 μm Polyacrylate Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Pharmaceutical, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Industrial Solvents on Equity®-1701

From our library of Articles, Sigma-Aldrich presents GC Analysis of Industrial Solvents on Equity®-1701
Keywords: Chromatography, Flame ionization detector, Gas chromatography

GC Analysis of Industrial Solvents on Equity®-1

From our library of Articles, Sigma-Aldrich presents GC Analysis of Industrial Solvents on Equity®-1
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of Industrial Solvents on SUPELCOWAX 10

From our library of Articles, Sigma-Aldrich presents GC Analysis of Industrial Solvents on SUPELCOWAX 10
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Volatiles in Water on Equity®-1 after SPME using 30 μm PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles in Water on Equity®-1 after SPME using 30 μm PDMS Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Volatiles in Water on SPB®-1 after SPME using 100 μm PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles in Water on SPB®-1 after SPME using 100 μm PDMS Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Solid phase microextractions

GC Analysis of Volatiles on SPB®-624, Direct Injection

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles on SPB®-624, Direct Injection
Keywords: Chromatography, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of Volatiles on VOCOL® after SPME using 75 μm Carboxen/PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles on VOCOL® after SPME using 75 μm Carboxen/PDMS Fiber
Keywords: Chromatography, Gas chromatography, Mass spectrometry, Purification, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Xylene Isomers on SLB®-IL60

From our library of Articles, Sigma-Aldrich presents GC Analysis of Xylene Isomers on SLB®-IL60
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Separation, Size-exclusion chromatography

GC Analysis of a 56-Component Industrial Solvents Mix on SLB®-IL60, Comparison to a Polyethylene Glycol (PEG) Column

From our library of Articles, Sigma-Aldrich presents GC Analysis of a 56-Component Industrial Solvents Mix on SLB®-IL60, Comparison to a Polyethylene Glycol (PEG) Column
Keywords: Chromatography, Flame ionization detector, Gas chromatography

US EPA Method 502.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap, ELCD Signal

From our library of Articles, Sigma-Aldrich presents US EPA Method 502.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap, ELCD Signal
Keywords: Chromatography, Gas chromatography, Hall electrolytic conductivity detector, Photo-ionization detector, Purge and trap, Sample preparations

US EPA Method 502.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap, PID Signal

From our library of Articles, Sigma-Aldrich presents US EPA Method 502.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap, PID Signal
Keywords: Chromatography, Gas chromatography, Hall electrolytic conductivity detector, Photo-ionization detector, Purification

US EPA Method 524.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 524.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap
Keywords: Chromatography, Gas chromatography, Purification, Size-exclusion chromatography

US EPA Method 624: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 624: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 624: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 624: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 624: GC Analysis of Volatiles on VOCOL® (60 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 624: GC Analysis of Volatiles on VOCOL® (60 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap
Keywords: Chromatography, Gas chromatography, Purification, Size-exclusion chromatography

US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Gas chromatography, Gas chromatography mass spectrometry, Mass spectrometry, Purge and trap, Purification, Solid phase microextractions

US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 8260: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 8260: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 8260: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 8260: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap
Keywords: Chromatography, Gas chromatography, Purification, Solid phase microextractions

US EPA Method OLM04.2 VOA: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method OLM04.2 VOA: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method OLM04.2 VOA: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method OLM04.2 VOA: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method TO-17: GC Analysis of Volatiles on Equity®-1 after Collection/Desorption using Carbotrap 300 Tube

From our library of Articles, Sigma-Aldrich presents US EPA Method TO-17: GC Analysis of Volatiles on Equity®-1 after Collection/Desorption using Carbotrap 300 Tube
Keywords: Chromatography, Gas chromatography

US EPA Method TO-17: GC Analysis of Volatiles on VOCOL® after Collection/Desorption using Air Toxics Tube

From our library of Articles, Sigma-Aldrich presents US EPA Method TO-17: GC Analysis of Volatiles on VOCOL® after Collection/Desorption using Air Toxics Tube
Keywords: Air Monitoring, Chromatography, Flame ionization detector, Gas chromatography, Purification

Peer-Reviewed Papers
15

References

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