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Aldicarb-(N-methyl-13C,d3 carbamoyl-13C)

PESTANAL®, analytical standard

Synonym: (1E)-2-Methyl-2-(methylthio)-O-[(methyl-13C-d3-amino)carbonyl-13C]oxime propanal

  • CAS Number 1261170-75-5

  • Empirical Formula (Hill Notation) 13C2C5D3H11N2O2S

  • Molecular Weight 195.27

  •  MDL number MFCD17677362

  •  PubChem Substance ID 329751422

  •  NACRES NA.24

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Properties

Related Categories A-B, Alpha Index of All Pesticide Standards, Analytical Standards, Analytical/Chromatography, Labeled Pesticide Standards,
Quality Level   100
grade   analytical standard
description   Isotopic Enrichment ≥98%
product line   PESTANAL®
assay   ≥98.5% (HPLC)
shelf life   limited shelf life, expiry date on the label
Featured Industry   Agriculture
Environmental
mass shift   M+5
storage temp.   −20°C
  −20°C
SMILES string   [2H][13C]([2H])([2H])N[13C](=O)O\N=C\C(C)(C)SC
InChI   1S/C7H14N2O2S/c1-7(2,12-4)5-9-11-6(10)8-3/h5H,1-4H3,(H,8,10)/b9-5+/i3+1D3,6+1
InChI key   QGLZXHRNAYXIBU-FONWFMSDSA-N

Description

General description

Aldicarb-(N-methyl-13C,d3, carbamoyl-13C) is an isotope-labeled analog of aldicarb, a carbamate pesticide, used as an insecticide and nematicide for the control of pests in agriculture.

Application

Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The main advantage of using the IDMS technique is because isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analog, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Analysis Note

Isotopic Enrichment ≥98%

Legal Information

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN2811 - class 6.1 - PG 1 - MP - RQ - Toxic solids, organic, n.o.s. HI: all
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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