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228036 Sigma-Aldrich

OXONE®, monopersulfate compound

Synonym: Potassium peroxymonosulfate

  • CAS Number 70693-62-8

  • Linear Formula KHSO5 · 0.5KHSO4 · 0.5K2SO4

  • Molecular Weight 307.38

  •  MDL number MFCD00040551

  •  PubChem Substance ID 57648006

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Properties

Related Categories Chemical Synthesis, Oxidizing Agents, Sulfur-Based, Synthetic Reagents
InChI Key   HJKYXKSLRZKNSI-UHFFFAOYSA-I

Description

General description

OXONE®, monopersulfate compound is a potassium triple salt mainly used as a stable, easy to handle and nontoxic oxidant.

Application

A rapid, efficient synthesis of oxaziridines from imines using buffered OXONE has been reported. Also used to study fading of an artist′s colorants.

OXONE®, monopersulfate compound may be used as an alternative to transition-metal oxidants for the conversion of aldehydes to carboxylic acids or esters.

Oxidant used for halogenation of α,β-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation.

Oxidant used for halogenation of a,b-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation.

2-Iodoxybenzenesulfonic Acid as an Extremely Active Catalyst for the Selective Oxidation of Alcohols to Aldehydes, Ketones, Carboxylic Acids, and Enones with Oxone

A Convenient Halogenation of α,β-Unsaturated Carbonyl Compounds with OXONE® and Hydrohalic Acid (HBr, HCl)

Packaging

1 kg in poly bottle

5 g in glass bottle

5 kg in poly drum

100 g in poly bottle

25 kg in fiber drum

Legal Information

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
RIDADR 
UN 3260 8 / PGII
WGK Germany 
2

Documents

Certificate of Analysis

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Certificate of Origin

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Protocols & Articles

Articles

Oxidizing and Reducing Agents

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis, and are some of the organic chemist’s most powerful tools for creating novel products. ...
ChemFiles Volume 1 Article 3
Keywords: Organic synthesis, Oxidations, Reductions

Peer-Reviewed Papers
15

References

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