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35660 Sigma-Aldrich

Bis(2-chloroethyl) ether

puriss., ≥99.0% (GC)

Synonym: 2,2′-Dichlorodiethyl ether

  • CAS Number 111-44-4

  • Linear Formula (ClCH2CH2)2O

  • Molecular Weight 143.01

  •  Beilstein/REAXYS Number 605317

  •  EC Number 203-870-1

  •  MDL number MFCD00000975

  •  PubChem Substance ID 329755200

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C2 to C7, Chemical Synthesis, Ethers, Organic Building Blocks,
Quality Level   200
vapor pressure   0.4 mmHg ( 20 °C)
grade   puriss.
assay   ≥99.0% (GC)
refractive index   n20/D 1.456 (lit.)
  n20/D 1.457
bp   65-67 °C/15 mmHg (lit.)
mp   −47 °C (lit.)
density   1.22 g/mL at 25 °C (lit.)
SMILES string   ClCCOCCCl
InChI   1S/C4H8Cl2O/c5-1-3-7-4-2-6/h1-4H2
InChI key   ZNSMNVMLTJELDZ-UHFFFAOYSA-N

Description

General description

Bis(2-chloroethyl) ether is a chemical intermediate. 2-Chloroethyl β-D-glucosiduronic acid is the major metabolite of bis(2-chloroethyl)ether.

Application

Bis(2-chloroethyl) ether may be used as a solvent and soil fumigant. It may be used in the preparation of macrocyclic polyethers, dibenzo-18-crown-6 polyether and dicyclohexyl-18-crown-6 polyether.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 1916 3(6.1) / PGII
WGK Germany 
WGK 2
RTECS 
KN0875000
Flash Point(F) 
131.0 °F - closed cup
Flash Point(C) 
55.0 °C - closed cup

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Protocols & Articles

Articles

US EPA Method 625: GC Analysis of Semivolatiles on SLB®-5ms

From our library of Articles, Sigma-Aldrich presents US EPA Method 625: GC Analysis of Semivolatiles on SLB®-5ms
Keywords: Chromatography, Gas chromatography, Purification

US EPA Method 8270: GC Analysis of Semivolatiles on Equity®-5

From our library of Articles, Sigma-Aldrich presents US EPA Method 8270: GC Analysis of Semivolatiles on Equity®-5
Keywords: Chromatography, Gas chromatography, Mass selective detector, Purification

US EPA Method 8270: GC Analysis of Semivolatiles on SLB-5ms (20 m x 0.18 mm I.D., 0.36 μm), Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 8270: GC Analysis of Semivolatiles on SLB-5ms (20 m x 0.18 mm I.D., 0.36 μm), Fast GC Analysis
Keywords: Chromatography, Gas chromatography, Purification

US EPA Method 8270: GC Analysis of Semivolatiles on SLB®-5ms (20 m x 0.18 mm I.D., 0.18 μm), Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 8270: GC Analysis of Semivolatiles on SLB®-5ms (20 m x 0.18 mm I.D., 0.18 μm), Fast GC Analysis
Keywords: Chromatography, Gas chromatography, Purification, Size-exclusion chromatography

US EPA Method 8270: GC Analysis of Semivolatiles on SLB®-5ms (20 m x 0.18 mm I.D., 0.36 μm), 28 °C/min Oven Ramp, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 8270: GC Analysis of Semivolatiles on SLB®-5ms (20 m x 0.18 mm I.D., 0.36 μm), 28 °C/min Oven Ramp, Fast GC Analysis
Keywords: Chromatography, Gas chromatography, Purification

US EPA Method 8270: GC Analysis of Semivolatiles on SLB®-5ms (30 m x 0.25 mm I.D., 0.50 μm)

From our library of Articles, Sigma-Aldrich presents US EPA Method 8270: GC Analysis of Semivolatiles on SLB®-5ms (30 m x 0.25 mm I.D., 0.50 μm)
Keywords: Chromatography, Gas chromatography, Purification

US EPA Method 8270: GC Analysis of Semivolatiles on SLB®-5ms, 350 °C Final Oven Temp.

From our library of Articles, Sigma-Aldrich presents US EPA Method 8270: GC Analysis of Semivolatiles on SLB®-5ms, 350 °C Final Oven Temp.
Keywords: Chromatography, Gas chromatography

US EPA Method 8270: GC Analysis of Semivolatiles on SLB®-5ms

From our library of Articles, Sigma-Aldrich presents US EPA Method 8270: GC Analysis of Semivolatiles on SLB®-5ms
Keywords: Chromatography, Gas chromatography, Purification

US EPA Method OLM04.2 SVOA: GC Analysis of Semivolatiles on SLB®-5ms

From our library of Articles, Sigma-Aldrich presents US EPA Method OLM04.2 SVOA: GC Analysis of Semivolatiles on SLB®-5ms
Keywords: Chromatography, Gas chromatography, Purification

Peer-Reviewed Papers
15

References

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