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62118 Supelco

(R)-(+)-Limonene

analytical standard

Synonym: (+)-p-Mentha-1,8-diene, (+)-Carvene, (R)-4-Isopropenyl-1-methyl-1-cyclohexene

  • CAS Number 5989-27-5

  • Empirical Formula (Hill Notation) C10H16

  • Molecular Weight 136.23

  •  Beilstein/REAXYS Number 2204754

  •  EC Number 227-813-5

  •  MDL number MFCD00062991

  •  PubChem Substance ID 329759707

  •  NACRES NA.24

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Properties

Related Categories 76/768/EEC Annex VIII, A-L, Additional Standards, All Alphabetically Sorted, Allergen Standards,
Quality Level   100
grade   analytical standard
vapor density   4.7 (vs air)
vapor pressure   <3 mmHg ( 14.4 °C)
assay   ≥99.0% (sum of enantiomers, GC)
form   neat
optical activity   [α]20/D +115.5±1°, c = 10% in ethanol
shelf life   limited shelf life, expiry date on the label
expl. lim.   6.1 %
application(s)   HPLC: suitable
  gas chromatography (GC): suitable
refractive index   n20/D 1.473 (lit.)
  n20/D 1.473
bp   176-177 °C (lit.)
density   0.842 g/mL at 20 °C (lit.)
Featured Industry   Agriculture
Cleaning Products
Cosmetics
Environmental
Food and Beverages
Personal Care
format   neat
storage temp.   2-8°C
SMILES string   CC(=C)[C@@H]1CCC(C)=CC1
InChI   1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m0/s1
InChI key   XMGQYMWWDOXHJM-JTQLQIEISA-N

Description

General description

(R)-(+)-Limonene is a terpenoid compound that is abundantly present in many plants such as rosemary. It is highly associated with plant and insect interactions due to its tendency to attract insects.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Regioselective hydrogenation of the exocyclic double bond; Regioselective epoxidation of the endocyclic double bond

Safety & Documentation

Safety Information

Signal word 
Danger
Hazard statements 
RIDADR 
UN 2052 3 / PGIII
WGK Germany 
3
RTECS 
GW6360000
Flash Point(F) 
123.8 °F
Flash Point(C) 
51 °C
Protocols & Articles

Articles

GC Analysis of Allergens in Perfume on SLB®-5ms (10 m x 0.10 mm I.D., 0.10 μm), Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents GC Analysis of Allergens in Perfume on SLB®-5ms (10 m x 0.10 mm I.D., 0.10 μm), Fast GC Analysis
Keywords: Chromatography, Cosmetics, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of Fragrance Compounds in Shampoo Base on a 100% Methyl Column after SPME using 100 μm PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Fragrance Compounds in Shampoo Base on a 100% Methyl Column after SPME using 100 μm PDMS Fiber
Keywords: Chromatography, Cosmetics, Gas chromatography, Mass selective detector, Purification, Solid phase microextractions

GC Analysis of Geranium Bourbon Essential Oil on SUPELCOWAX® 10

From our library of Articles, Sigma-Aldrich presents GC Analysis of Geranium Bourbon Essential Oil on SUPELCOWAX® 10
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of Lemon Essential Oil on SLB®-5ms (10 m x 0.10 mm I.D., 0.10 μm), Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents GC Analysis of Lemon Essential Oil on SLB®-5ms (10 m x 0.10 mm I.D., 0.10 μm), Fast GC Analysis
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of Sweet Orange Essential Oil on SLB®-5ms (10 m x 0.10 mm I.D., 0.10 μm), Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents GC Analysis of Sweet Orange Essential Oil on SLB®-5ms (10 m x 0.10 mm I.D., 0.10 μm), Fast GC Analysis
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of Volatiles in Limoncello on SLB®-5ms after SPME using a 100 μm PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles in Limoncello on SLB®-5ms after SPME using a 100 μm PDMS Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Mass spectrometry, Purification, Sample preparations, Solid phase microextractions

GC Analysis of Volatiles in Roasted Coffee Beans on Omegawax® after SPME using a 50/30 μm DVB/Carboxen/PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles in Roasted Coffee Beans on Omegawax® after SPME using a 50/30 μm DVB/Carboxen/PDMS Fiber
Keywords: Chromatography, Gas chromatography, Mass spectrometry, Purification, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of an Indoor Air Standard on Equity®-1

From our library of Articles, Sigma-Aldrich presents GC Analysis of an Indoor Air Standard on Equity®-1
Keywords: Air Monitoring, Chromatography, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of cis/trans Limonene Oxide Enantiomers on Astec® CHIRALDEX® B-PH

From our library of Articles, Sigma-Aldrich presents GC Analysis of cis/trans Limonene Oxide Enantiomers on Astec® CHIRALDEX® B-PH
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GCxGC Analysis of Allergens in Perfume Sample 1 on SLB®-5ms x SLB®-35ms, Non-Polar to Polar Strategy

From our library of Articles, Sigma-Aldrich presents GCxGC Analysis of Allergens in Perfume Sample 1 on SLB®-5ms x SLB®-35ms, Non-Polar to Polar Strategy
Keywords: Allergens, Chromatography, Cosmetics, Gas chromatography, Mass spectrometry, Phase transitions, Size-exclusion chromatography

GCxGC Analysis of Allergens in Perfume Sample 2 on SLB®-5ms x SLB®-35ms, Non-Polar to Polar Strategy

From our library of Articles, Sigma-Aldrich presents GCxGC Analysis of Allergens in Perfume Sample 2 on SLB®-5ms x SLB®-35ms, Non-Polar to Polar Strategy
Keywords: Allergens, Chromatography, Cosmetics, Gas chromatography, Mass spectrometry, Phase transitions, Size-exclusion chromatography

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Peer-Reviewed Papers
15

References

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