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89680 Supelco

Toluene

analytical standard

  • CAS Number 108-88-3

  • Linear Formula C6H5CH3

  • Molecular Weight 92.14

  •  Beilstein/REAXYS Number 635760

  •  EC Number 203-625-9

  •  MDL number MFCD00008512

  •  eCl@ss 39011102

  •  PubChem Substance ID 329769525

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Properties

Related Categories Additional Standards, Alpha Sort, Analytical Standards, Analytical/Chromatography, Aromatics,
grade   analytical standard
vapor density   3.2 (vs air)
vapor pressure   22 mmHg ( 20 °C)
  26 mmHg ( 25 °C)
InChI Key   YXFVVABEGXRONW-UHFFFAOYSA-N
assay   ≥99.9% (GC)
form   neat
autoignition temp.   997 °F
shelf life   limited shelf life, expiry date on the label
expl. lim.   7 %
application(s)   HPLC: suitable
  gas chromatography (GC): suitable
refractive index   n/D 1.496 (lit.)
bp   110-111 °C (lit.)
mp   -93 °C (lit.)
density   0.865 g/mL at 25 °C (lit.)
Featured Industry   Environmental
format   neat

Description

General description

Toluene is an aromatic hydrocarbon, which can be obtained from crude oil via cracking or distillation process.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Packaging

5, 25 mL in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN1294 - class 3 - PG 2 - Toluene
WGK Germany 
3
RTECS 
XS5250000
Flash Point(F) 
39.2 °F
Flash Point(C) 
4 °C

Documents

Certificate of Analysis

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Protocols & Articles

Articles

ASTM D5134: GC Analysis of Hydrocarbons on Petrocol® DH 50.2

This application demonstrates the suitability of the Petrocol column for the efficient analysis of hydrocarbons as listed in ASTM method D5134.
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

ASTM D6526: GC Analysis of Impurities in Toluene on SLB®-IL100, 30 m Column

From our library of Articles, Sigma-Aldrich presents ASTM D6526: GC Analysis of Impurities in Toluene on SLB®-IL100, 30 m Column
Keywords: Chromatography, Flame ionization detector, Gas chromatography

ASTM D6526: GC Analysis of Impurities in Toluene on SLB®-IL100, 60 m Column

From our library of Articles, Sigma-Aldrich presents ASTM D6526: GC Analysis of Impurities in Toluene on SLB®-IL100, 60 m Column
Keywords: Chromatography, Gas chromatography

GC Analysis of Aromatics in reforulated Gasoline on Equity®-1

From our library of Articles, Sigma-Aldrich presents GC Analysis of Aromatics in reforulated Gasoline on Equity®-1
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Aromatics in reforulated Gasoline on SLB®-IL111

From our library of Articles, Sigma-Aldrich presents GC Analysis of Aromatics in reforulated Gasoline on SLB®-IL111
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Separation

GC Analysis of Aromatics in reforulated Gasoline on SUPELCOWAX® 10

From our library of Articles, Sigma-Aldrich presents GC Analysis of Aromatics in reforulated Gasoline on SUPELCOWAX® 10
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of BTEX, Undecane, and Tridecane on SLB®-IL100

From our library of Articles, Sigma-Aldrich presents GC Analysis of BTEX, Undecane, and Tridecane on SLB®-IL100
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Class 2 Residual Solvents on Equity®-1 after SPME using 85 μm Polyacrylate Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Class 2 Residual Solvents on Equity®-1 after SPME using 85 μm Polyacrylate Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Pharmaceutical, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Class 2 Residual Solvents on OVI-G43

From our library of Articles, Sigma-Aldrich presents GC Analysis of Class 2 Residual Solvents on OVI-G43
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Pharmaceutical, Size-exclusion chromatography

GC Analysis of Class 2 Residual Solvents on VOCOL® after SPME using 85 μm Polyacrylate Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Class 2 Residual Solvents on VOCOL® after SPME using 85 μm Polyacrylate Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Pharmaceutical, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Gasoline Residue in Arson Samples on a 100% Methyl Column after SPME using 100 μm PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Gasoline Residue in Arson Samples on a 100% Methyl Column after SPME using 100 μm PDMS Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Sample preparations, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Hydrocarbons in Gasoline on Equity®-1 (15 m x 0.10 mm I.D., 0.10 μm), Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents GC Analysis of Hydrocarbons in Gasoline on Equity®-1 (15 m x 0.10 mm I.D., 0.10 μm), Fast GC Analysis
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Size-exclusion chromatography

GC Analysis of Hydrocarbons in Gasoline on Petrocol® DH, Isothermal

From our library of Articles, Sigma-Aldrich presents GC Analysis of Hydrocarbons in Gasoline on Petrocol® DH, Isothermal
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Separation

GC Analysis of Hydrocarbons in Gasoline on Petrocol® DH

From our library of Articles, Sigma-Aldrich presents GC Analysis of Hydrocarbons in Gasoline on Petrocol® DH
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of Industrial Solvents on Equity®-1701

From our library of Articles, Sigma-Aldrich presents GC Analysis of Industrial Solvents on Equity®-1701
Keywords: Chromatography, Flame ionization detector, Gas chromatography

GC Analysis of Industrial Solvents on Equity®-1

From our library of Articles, Sigma-Aldrich presents GC Analysis of Industrial Solvents on Equity®-1
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of Industrial Solvents on SUPELCOWAX 10

From our library of Articles, Sigma-Aldrich presents GC Analysis of Industrial Solvents on SUPELCOWAX 10
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Ionic Liquid Test Mix on SLB®-IL100 (15 m x 0.10 mm I.D., 0.08 μm)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Ionic Liquid Test Mix on SLB®-IL100 (15 m x 0.10 mm I.D., 0.08 μm)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Ionic Liquid Test Mix on SLB®-IL100 (30 m x 0.25 mm I.D., 0.20 μm)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Ionic Liquid Test Mix on SLB®-IL100 (30 m x 0.25 mm I.D., 0.20 μm)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Ionic Liquid Test Mix on SLB®-IL59 (15 m x 0.10 mm I.D., 0.08 μm)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Ionic Liquid Test Mix on SLB®-IL59 (15 m x 0.10 mm I.D., 0.08 μm)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Ionic Liquid Test Mix on SLB®-IL59 (30 m x 0.25 mm I.D., 0.20 μm)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Ionic Liquid Test Mix on SLB®-IL59 (30 m x 0.25 mm I.D., 0.20 μm)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Ionic Liquid Test Mix on SLB®-IL76 (15 m x 0.10 mm I.D., 0.08 μm)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Ionic Liquid Test Mix on SLB®-IL76 (15 m x 0.10 mm I.D., 0.08 μm)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Ionic Liquid Test Mix on SLB®-IL76 (30 m x 0.25 mm I.D., 0.20 μm)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Ionic Liquid Test Mix on SLB®-IL76 (30 m x 0.25 mm I.D., 0.20 μm)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Refinery Grade Unleaded Gasoline on TCEP (15 m x 0.10 mm I.D., 0.18 μm), Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents GC Analysis of Refinery Grade Unleaded Gasoline on TCEP (15 m x 0.10 mm I.D., 0.18 μm), Fast GC Analysis
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Solvents on a Packed Column (3% SP-1500 on Carbopack™ B)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Solvents on a Packed Column (3% SP-1500 on Carbopack™ B)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of TCEP Test Mix on SLB®-IL100, 100 °C Oven Temp.

From our library of Articles, Sigma-Aldrich presents GC Analysis of TCEP Test Mix on SLB®-IL100, 100 °C Oven Temp.
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of TCEP Test Mix on SLB®-IL100, 110 °C Oven Temp.

From our library of Articles, Sigma-Aldrich presents GC Analysis of TCEP Test Mix on SLB®-IL100, 110 °C Oven Temp.
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of TCEP Test Mix on SLB®-IL100, 80 °C Oven Temp.

From our library of Articles, Sigma-Aldrich presents GC Analysis of TCEP Test Mix on SLB®-IL100, 80 °C Oven Temp.
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Volatiles in Water on Equity®-1 after SPME using 30 μm PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles in Water on Equity®-1 after SPME using 30 μm PDMS Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Volatiles in Water on SPB®-1 after SPME using 100 μm PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles in Water on SPB®-1 after SPME using 100 μm PDMS Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Solid phase microextractions

GC Analysis of Volatiles on SPB®-624, Direct Injection

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles on SPB®-624, Direct Injection
Keywords: Chromatography, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of Volatiles on VOCOL® after SPME using 75 μm Carboxen/PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles on VOCOL® after SPME using 75 μm Carboxen/PDMS Fiber
Keywords: Chromatography, Gas chromatography, Mass spectrometry, Purification, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Xylene Isomers on SLB®-IL60

From our library of Articles, Sigma-Aldrich presents GC Analysis of Xylene Isomers on SLB®-IL60
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Separation, Size-exclusion chromatography

GC Analysis of a 56-Component Industrial Solvents Mix on SLB®-IL60, Comparison to a Polyethylene Glycol (PEG) Column

From our library of Articles, Sigma-Aldrich presents GC Analysis of a 56-Component Industrial Solvents Mix on SLB®-IL60, Comparison to a Polyethylene Glycol (PEG) Column
Keywords: Chromatography, Flame ionization detector, Gas chromatography

HPLC Analysis of Benzene and Deuterated Benzene on Ascentis® Express C18

From our library of Articles, Sigma-Aldrich presents HPLC Analysis of Benzene and Deuterated Benzene on Ascentis® Express C18
Keywords: Chromatography, High performance liquid chromatography

HPLC Analysis of Column Test Mix on Discovery® BIO Wide Pore C18, Effect of HPLC Column I.D. on Sensitivity

From our library of Articles, Sigma-Aldrich presents HPLC Analysis of Column Test Mix on Discovery® BIO Wide Pore C18, Effect of HPLC Column I.D. on Sensitivity
Keywords: Chromatography, High performance liquid chromatography

HPLC Analysis of Polar and Non-Polar Analytes on Ascentis® Express C18, Column Test Mixture

From our library of Articles, Sigma-Aldrich presents HPLC Analysis of Polar and Non-Polar Analytes on Ascentis® Express C18, Column Test Mixture
Keywords: Chromatography, High performance liquid chromatography, Pharmaceutical

HPLC Analysis of Polar and Non-Polar Analytes on Ascentis® Express C8, Column Test Mixture

From our library of Articles, Sigma-Aldrich presents HPLC Analysis of Polar and Non-Polar Analytes on Ascentis® Express C8, Column Test Mixture
Keywords: Chromatography, High performance liquid chromatography, Pharmaceutical

The Utility of Headspace Grade Solvents for the Analysis of Organic Volatile Impurities

Organic volatile impurities or “OVIs” sometimes remain behind in pharmaceutical preparations as a result of synthetic and manufacturing procedures. For reasons of health and safety, testing is done t...
Katherine Stenerson, Shyam Verma
Reporter US Volume 28.1
Keywords: Chromatography, Gas chromatography, Organic synthesis, Pharmaceutical, Solvents

UHPLC Analysis of Deuterated Isomers on Titan™ C18

From our library of Articles, Sigma-Aldrich presents UHPLC Analysis of Deuterated Isomers on Titan™ C18
Keywords: Anticonvulsants, Chromatography

US EPA Method 0030: GC Analysis of Volatiles on SPB®-624 after Collection/Desorption using VOST 100 Tube

From our library of Articles, Sigma-Aldrich presents US EPA Method 0030: GC Analysis of Volatiles on SPB®-624 after Collection/Desorption using VOST 100 Tube
Keywords: Air Monitoring, Chromatography, Flame ionization detector, Gas chromatography, Purification

US EPA Method 502.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap, ELCD Signal

From our library of Articles, Sigma-Aldrich presents US EPA Method 502.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap, ELCD Signal
Keywords: Chromatography, Gas chromatography, Hall electrolytic conductivity detector, Photo-ionization detector, Purge and trap, Sample preparations

US EPA Method 502.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap, PID Signal

From our library of Articles, Sigma-Aldrich presents US EPA Method 502.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap, PID Signal
Keywords: Chromatography, Gas chromatography, Hall electrolytic conductivity detector, Photo-ionization detector, Purification

US EPA Method 524.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 524.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap
Keywords: Chromatography, Gas chromatography, Purification, Size-exclusion chromatography

US EPA Method 624: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 624: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 624: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 624: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 624: GC Analysis of Volatiles on VOCOL® (60 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 624: GC Analysis of Volatiles on VOCOL® (60 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap
Keywords: Chromatography, Gas chromatography, Purification, Size-exclusion chromatography

US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on Equity®-1 (15 m x 0.10 mm I.D., 0.10 μm), Direct Injection, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on Equity®-1 (15 m x 0.10 mm I.D., 0.10 μm), Direct Injection, Fast GC Analysis
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on Equity®-1 after Purge & Trap using "M" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on Equity®-1 after Purge & Trap using "M" Trap
Keywords: Chromatography, Environmental, Flame ionization detector, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on VOCOL® after Purge & Trap using "M" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on VOCOL® after Purge & Trap using "M" Trap
Keywords: Chromatography, Environmental, Flame ionization detector, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Gas chromatography, Gas chromatography mass spectrometry, Mass spectrometry, Purge and trap, Purification, Solid phase microextractions

US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 8260: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 8260: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 8260: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 8260: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap
Keywords: Chromatography, Gas chromatography, Purification, Solid phase microextractions

US EPA Method OLM04.2 VOA: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method OLM04.2 VOA: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method OLM04.2 VOA: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method OLM04.2 VOA: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method TO-17: GC Analysis of Volatiles on Equity®-1 after Collection/Desorption using Carbotrap 300 Tube

From our library of Articles, Sigma-Aldrich presents US EPA Method TO-17: GC Analysis of Volatiles on Equity®-1 after Collection/Desorption using Carbotrap 300 Tube
Keywords: Chromatography, Gas chromatography

US EPA Method TO-17: GC Analysis of Volatiles on VOCOL® after Collection/Desorption using Air Toxics Tube

From our library of Articles, Sigma-Aldrich presents US EPA Method TO-17: GC Analysis of Volatiles on VOCOL® after Collection/Desorption using Air Toxics Tube
Keywords: Air Monitoring, Chromatography, Flame ionization detector, Gas chromatography, Purification

Peer-Reviewed Papers
15

References

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