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205303 Sigma-Aldrich

Lithium perchlorate trihydrate

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Properties

Related Categories Chemical Synthesis, Essential Chemicals, Lithium Salts, Oxidizing Agents, Perchlorates,
Quality Level   100
assay   21-22% chlorine basis (silver nitrate titration)
form   crystals and lumps
density   1.841 g/mL at 25 °C (lit.)
SMILES string   [Li+].[H]O[H].[H]O[H].[H]O[H].[O-]Cl(=O)(=O)=O
InChI   1S/ClHO4.Li.3H2O/c2-1(3,4)5;;;;/h(H,2,3,4,5);;3*1H2/q;+1;;;/p-1
InChI key   JAWYRNYHJJDXHX-UHFFFAOYSA-M

Description

General description

Crystal structure of lithium perchlorate trihydrate (LiClO4.3H2O) has been investigated by X-ray and neutron diffraction studies. It exhibits pyroelectric properties.

Application

Lithium perchlorate trihydrate may be used to modify the membrane morphology of poly[(vinylidene fluoride)-co-trifluoroethylene] membranes, by doping it with varying concentrations of LiClO4.3H2O. It may be used to compose the polymer nanocomposite electrolyte (PNCE) films.

When used as a co-catalyst, accelerates the Baylis-Hillman reaction, the coupling of α,β-unsaturated carbonyls with aldehydes.

Packaging

1 kg in glass bottle

50, 250 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
UN 1481 5.1 / PGII
WGK Germany 
WGK 1
RTECS 
SC8750000
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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