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206911 Sigma-Aldrich

Aluminum chloride

reagent grade, 98%

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Properties

Related Categories Acids, Acids & Bases, Aluminum, Aluminum Catalysts, Aluminum Salts,
Quality Level   100
grade   reagent grade
vapor pressure   1 mmHg ( 100 °C)
assay   98%
mp   190 °C (lit.)
SMILES string   Cl[Al](Cl)Cl
InChI   1S/Al.3ClH/h;3*1H/q+3;;;/p-3
InChI key   VSCWAEJMTAWNJL-UHFFFAOYSA-K

Description

General description

Aluminum chloride participates in the amination of exo-2-chloronorbornane to afford 2-azabicyclo[3.2.1]octane, small amounts of the 3-isomer and exo-2-aminonorbornane. It has been reported to promote the Friedel-Crafts acylation of 4-tert-butylbenzoyl chloride with mesitylene.

Application

Aluminum chloride has been employed for the estimation of total contents of flavonoids in a freeze-dried extract isolated from Issopus officinalis. It has been employed for the synthesis of the following compounds:
• 3′-methyl-5′,6′,7′,7a′-tetrahydro-4′H-spiro(cyclohexane-1,1′-isobenzofuran)
• trans-methyl 2-(cyclohex-1-enyl)cyclohexyl ketone
• 1,1,3-trimethyl-1,4,5,6,7,7a-hexahydroisobenzofuran
• 1-((2R*,4aS*,8aR*)-2-methyldecahydronaphthalen-4ayl)ethanone

Aluminum chloride may be used as catalyst for the Friedel-Crafts polymerizations of 4-(trifluoromethoxy)benzyl bromide. It may be employed as catalyst for Fries rearrangement of phenyl isobutyrate at 140°C to afford a mixture of 2-hydroxy- and 4-hydroxy-isobutyrophenone.
It may be used to catalyze:
• Degradation of polystyrene to benzene.
• Carbonization of polycyclic aromatic hydrocarbons.
• Colorimetric microassay of hydroperoxides.

Packaging

1 kg in glass bottle

100 g in glass bottle

Features and Benefits

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Aluminum nitride can be synthesized from the elemnts with AlCl3 added to help facilitate crystallization.

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Supplemental Hazard Statements 
EUH014
RIDADR 
UN 1726 8 / PGII
WGK Germany 
WGK 1
RTECS 
BD0525000
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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References

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