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213225 Sigma-Aldrich

Lithium bromide

ReagentPlus®, ≥99%

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Properties

Related Categories Essential Chemicals, Lithium Salts, Research Essentials, Salts
Quality Level   100
vapor pressure   1 hPa ( 748 °C)
product line   ReagentPlus®
assay   ≥99%
form   powder
pH   7 (20 °C, 10 g/L)
mp   550 °C (lit.)
SMILES string   [Li+].[Br-]
InChI   1S/BrH.Li/h1H;/q;+1/p-1
InChI key   AMXOYNBUYSYVKV-UHFFFAOYSA-M

Description

General description

LiBr/Chlorotrimethylsilane reagent participates in the conversion of alcohols to bromides.

Application

Lithium bromide (LiBr) may be employed as a catalyst in the following studies:
• Transformation of (aromatic- and α,β-unsaturated) aldehydes to dithioacetals via solvent-free dithioacetalization.
• Synthesis of olefins via condensation reaction of carbonyl compounds with active methylene compounds.
• Green synthesis of β-amino alcohols.
• Chemo- and regioselective bromination of aromatic compounds was carried out by employing LiBr/ceric ammonium nitrate (CAN) reagent system (as a source of Br+ ion).

Packaging

100, 500 g in poly bottle

2 kg in poly bottle

Other Notes

Go to Redi-Dri Product Listing 746479

Legal Information

ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 1
RTECS 
OJ5755000
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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