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216763 Sigma-Aldrich

Hydrogen peroxide solution

Green Alternative

contains inhibitor, 30 wt. % in H2O, ACS reagent

  • CAS Number 7722-84-1

  • Empirical Formula (Hill Notation) H2O2

  • Molecular Weight 34.01

  •  Beilstein Registry Number 3587191

  •  MDL number MFCD00011333

  •  PubChem Substance ID 329752192

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Properties

Related Categories 12 Principles Aligned Products, Acids & Bases, Blocking Sera and Reagents, Chemical Synthesis, Core Bioreagents,
grade   ACS reagent
vapor density   1 (vs air)
vapor pressure   23.3 mmHg ( 30 °C)
InChI Key   MHAJPDPJQMAIIY-UHFFFAOYSA-N
assay   29.0-32.0% (ACS specification)
quality   stabilized
greener alternative product characteristics   Catalysis
Learn more about the Principles of Green Chemistry.
concentration   30 wt. % in H2O
impurities   ≤0.0006 meq/g Titr. acid
evapn. residue   ≤0.002%
color   APHA: ≤10
anion traces   chloride (Cl-): ≤3 ppm
  nitrate (NO3-): ≤2 ppm
  phosphate (PO43-): ≤2 ppm
  sulfate (SO42-): ≤5 ppm
cation traces   Fe: ≤0.5 ppm
  NH4+: ≤5 ppm
  heavy metals (as Pb): ≤1 ppm
storage temp.   2-8°C

Description

Packaging

100, 500 mL in poly bottle

4 L in poly drum

Application

Greener oxidant used for bromination of 1,3-dicarbonyl compounds, amide bond formation from amines and aldehydes, halogenation of aromatic compounds and dethioacetalization.

Highly Selective Oxidative Monochlorination To Synthesize Organic Intermediates: 2-Chlorotoluene, 2-Chloroaniline, 2-Chlorophenol, and 2-Chloro-4-methylphenol

Hydrogen peroxide solution has also been used in the preparation of ′Piranha′, a sulfuric acid/hydrogen peroxide mixture for cleaning silicon wafers used in nanostructure-initiator mass spectrometry (NIMS) chips.
It can be used as an oxidant for:
• Epoxidation of terminal olefins under halide-free conditions.
• Oxidation of cyclohexene to adipic acid under organic solvent- and halide-free conditions.

Hydrogen peroxide solution has been used in an immunoblotting protocol.

General description

Hydrogen peroxide solution is commonly used as a bleaching agent. It shows germicidal and sporicidal properties. H2O2 is a reactive oxygen species formed as a reaction product of various aerobic metabolic processes. Its ultra-trace quantification in the concentration range of 10-11mole/ml by a fluorometric method has been described.

Other Notes

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 2014 8(5.1) / PGII
WGK Germany 
1

Frequently Asked Questions

Which document(s) contains shelf-life or expiration date information for a given product?
If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.
How do I get lot-specific information or a Certificate of Analysis?
The lot specific COA document can be found by entering the lot number above under the "Documents" section.
How do I find price and availability?
There are several ways to find pricing and availability for our products.Once you log onto our website, you will find the price and availability displayed on the product detail page.You can contact any of our Customer Sales and Service offices to receive a quote. USA customers: 1-800-325-3010 orview local office numbers.
What is the Department of Transportation shipping information for this product?
Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
What is the molarity of Product 216763, Hydrogen peroxide solution?
The molarity of 30% (w/w) hydrogen peroxide is approximately 9.8 M.
What is the stabilizer in Product 216763, Hydrogen peroxide solution?
The stabilizer is a proprietary mixture that the manufacturer does not disclose.
What is the pH of Product 216763, Hydrogen peroxide solution?
This product will give an apparent pH that is less than 4.This is an apparent pH and not a real pH since hydrogen peroxide is not ionized at that pH.
What is the density of 30% hydrogen peroxide in water, Product 216763, Hydrogen peroxide solution?
According to the Merck Index, the density is about 1.11 g/mL.
My question is not addressed here, how can I contact Technical Service for assistance?
Ask a Scientist here.
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Protocols & Articles
Peer-Reviewed Papers
15

References

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