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249866 Sigma-Aldrich

Titanium(IV) chloride solution

1.0 M in methylene chloride

Synonym: Titanium tetrachloride

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Properties

Related Categories Acids, Acids & Bases, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals,
vapor pressure   24.09 psi ( 55 °C)
  6.93 psi ( 20 °C)
InChI Key   XJDNKRIXUMDJCW-UHFFFAOYSA-J
concentration   1.0 M in methylene chloride
density   1.365 g/mL at 25 °C

Description

General description

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl4 having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) are used to synthesize nanosized titanium dioxide.

Application

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.

Packaging

100, 4×100, 800 mL in Sure/Seal™

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Target organs 
Blood, Central nervous system, Liver
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN3289 - class 6.1 - PG 2 - acidic - Toxic liquid, corrosive, inorganic, n.o.s., HI: all
WGK Germany 
2

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Single- & multi-channel pipettes from BRAND
Protocols & Articles

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Peer-Reviewed Papers
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References

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