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34866 Sigma-Aldrich

Toluene

for HPLC, 99.9%

  • CAS Number 108-88-3

  • Linear Formula C6H5CH3

  • Molecular Weight 92.14

  •  Beilstein/REAXYS Number 635760

  •  EC Number 203-625-9

  •  MDL number MFCD00008512

  •  eCl@ss 39011102

  •  PubChem Substance ID 329755074

  •  NACRES NA.21

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Properties

Related Categories Amber Glass Bottles, Analytical Reagents, Analytical/Chromatography, Chromatography Reagents & Solvents, HPLC,
Quality Level   100
grade   for HPLC
vapor density   3.2 (vs air)
vapor pressure   22 mmHg ( 20 °C)
  26 mmHg ( 25 °C)
assay   99.9%
autoignition temp.   997 °F
expl. lim.   7 %
impurities   ≤0.0005% non-volatile matter
  ≤0.0005% thiophene
  ≤0.001% free acid (as HCl)
  ≤0.02% water (Karl Fischer)
refractive index   n/D 1.496 (lit.)
bp   110-111 °C (lit.)
mp   -93 °C (lit.)
density   0.865 g/mL at 25 °C (lit.)
UV absorption   λ: 286 nm Amax: ≤1.00
  λ: 288 nm Amax: ≤0.50
  λ: 293 nm Amax: ≤0.20
  λ: 300 nm Amax: ≤0.10
  λ: 310 nm Amax: ≤0.05
  λ: 335 nm Amax: ≤0.02
  λ: 350 nm Amax: ≤0.004
Featured Industry   Food and Beverages
SMILES string   Cc1ccccc1
InChI   1S/C7H8/c1-7-5-3-2-4-6-7/h2-6H,1H3
InChI key   YXFVVABEGXRONW-UHFFFAOYSA-N

Description

General description

Toluene, a benzene analog, is widely employed as an organic solvent. It has been reported to be a biotoxic solvent (toxic to many microorganisms at 0.1%v/v concentrations). Its anaerobic biodegradation to CO2, by the denitrifying bacterium Thauera arornatica has been reported. It forms a syndiotactic polystyrene-toluene molecular compound. Crystal structure of this molecular compound has been investigated by X-ray diffraction studies.

Application

Toluene may be used as a doping agent during the quantitative estimation of triacylglycerols (TAGs) by liquid chromatography-atmospheric pressure photoionization-mass spectrometry (LC-APPIMS). It has been reported to improve the sensitivity of analysis. It may be used as solvent for the preparation of 4-arm polylactide-based (PLA) star oligomer.

Packaging

1, 6×1, 2, 4×2, 4×4 L in glass bottle

20 L in Nowpak™

View returnable container options.

100 mL in glass bottle

200 L in Pure-Pac™ 1

Other Notes

Important notice
• The article number 34866-4X2.5L will be discontinued. Please order the single bottle 34866-2.5L which is physically identical with the same exact specifications.
• The article number 34866-6X1L will be discontinued. Please order the single bottle 34866-1L which is physically identical with the same exact specifications.

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Target organs 
Central nervous system
RIDADR 
UN1294 - class 3 - PG 2 - Toluene
WGK Germany 
WGK 2
RTECS 
XS5250000
Flash Point(F) 
39.2 °F
Flash Point(C) 
4.0 °C

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Dispensette™ S
Protocols & Articles

Articles

GC Analysis of Pesticides in Spinach on SLB®-5ms after QuEChERS Extraction then SPE Clean-up using Supelclean™ ENVI-Carb/NH2 Dual Layer

From our library of Articles, Sigma-Aldrich presents GC Analysis of Pesticides in Spinach on SLB®-5ms after QuEChERS Extraction then SPE Clean-up using Supelclean™ ENVI-Carb/NH2 Dual Layer
Keywords: Chromatography, Gas chromatography, Mass spectrometry, Pesticides, Sample preparations, Solid phase extractions

GC Analysis of Pesticides in Spinach on SLB®-5ms after QuEChERS Extraction then SPE Clean-up using Supel™ Sphere Carbon/NH2

From our library of Articles, Sigma-Aldrich presents GC Analysis of Pesticides in Spinach on SLB®-5ms after QuEChERS Extraction then SPE Clean-up using Supel™ Sphere Carbon/NH2
Keywords: Chromatography, Filtration, Gas chromatography, Mass spectrometry, Pesticides, Sample preparations, Solid phase extractions

Pressure-Temperature Calculator for Solvents

*Calculations provide estimated results based on Antoine's Coefficients and their associated temperature range values. Antoine's Coefficients were obtained from the National Institute of Standards an...

Screening for Estrogen Active Nonylphenols in Water by Planar Solid Phase Extraction – Planar Yeast Estrogen Screen

Nonylphenols (NP) are ubiquitous substances that have been detected in highly diverse foodstuff and that inter alia show estrogenic activity.1,2 NP can presumably end up in the aquatic environment as...
Keywords: Chromatography, Environmental, Hormones, Solid phase extractions

Peer-Reviewed Papers
15

References

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