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C9794 Sigma-Aldrich

(±)-Z-Phosphonoglycine trimethyl ester

Synonym: (±)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl) acetate, (±)-Trimethyl Z-phosphonoglycinate

  • CAS Number 88568-95-0

  • Linear Formula (CH3O)2P(O)CH(NHCO2CH2C6H5)CO2CH3

  • Molecular Weight 331.26

  •  Beilstein/REAXYS Number 5764460

  •  MDL number MFCD00043304

  •  PubChem Substance ID 329775210

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Properties

mp   77-80 °C (lit.)
storage temp.   2-8°C
SMILES string   COC(=O)C(NC(=O)OCc1ccccc1)P(=O)(OC)OC
InChI   1S/C13H18NO7P/c1-18-12(15)11(22(17,19-2)20-3)14-13(16)21-9-10-7-5-4-6-8-10/h4-8,11H,9H2,1-3H3,(H,14,16)
InChI key   GSYSFVSGPABNNL-UHFFFAOYSA-N

Description

Application

Starting material for the synthesis of (Z)-dehydroamino acids by Wittig-Horner reaction with aldehydes; the dehydroamino acids can be stereoselectively reduced to amino acids.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Protocols & Articles
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