Alkyl, Aryl and Alkenyl - Grignard reagent

Shop Alkyl, Aryl and Alkenyl Grignard reagents for chemical synthesis

Grignard reagents (RMgX) are organomagnesium halides formed by the reaction of magnesium metal with alkyl or alkenyl halides. They are very strong bases and react with acidic hydrogens such as alcohols, water and carboxylic acids. Sigma-Aldrich is pleased to present its comprehensive list of Grignard reagents for use in reactions such as Grignard reaction, Monsanto process, Ziegler–Natta process, Shell higher olefin process and Olefin metathesis.

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302430 Methylmagnesium bromide solution 1.0 M in dibutyl ether CH3BrMg
257087 Methylmagnesium bromide solution 3.0 M in diethyl ether CH3BrMg
189898 Methylmagnesium bromide solution 3.0 M in diethyl ether CH3BrMg
282235 Methylmagnesium bromide solution 1.4 M in THF: toluene (1:3) CH3BrMg
703583 Methylmagnesium bromide solution ~3.4 M in 2-methyltetrahydrofuran Green Alternative CH3BrMg
189901 Methylmagnesium chloride solution 3.0 M in THF CH3ClMg
293091 Methyl-d3-magnesium iodide solution 1.0 M in diethyl ether, 99 atom % D CD3IMg
254363 Methylmagnesium iodide solution 3.0 M in diethyl ether CH3IMg
345105 Ethylmagnesium bromide solution 1.0 M in tert-butyl methyl ether C2H5BrMg
189871 Ethylmagnesium bromide solution 3.0 M in diethyl ether C2H5BrMg
364673 Ethylmagnesium bromide solution 1.0 M in THF C2H5BrMg
703591 Ethylmagnesium bromide solution 3.4 M in 2-methyltetrahydrofuran Green Alternative C2H5BrMg
300330 Ethylmagnesium chloride solution 2.0 M in diethyl ether C2H5ClMg
303828 Ethylmagnesium chloride solution 2.0 M in THF C2H5ClMg
225754 Allylmagnesium bromide solution 1.0 M in diethyl ether C3H5BrMg
256609 Allylmagnesium bromide solution 1.0 M in diethyl ether C3H5BrMg
526797 Cyclopropylmagnesium bromide solution 0.5 M in THF C3H5BrMg
772844 Cyclopropylmagnesium bromide solution 1.0 M in 2-methyltetrahydrofuran Green Alternative C3H5BrMg
225908 Allylmagnesium chloride solution 2.0 M in THF C3H5ClMg
703567 Isopropylmagnesium bromide solution 2.9 M in 2-methyltetrahydrofuran Green Alternative C3H7BrMg
224383 Isopropylmagnesium chloride solution 2.0 M in diethyl ether C3H7ClMg
230111 Isopropylmagnesium chloride solution 2.0 M in THF C3H7ClMg
776270 n-Propylmagnesium chloride solution 1.0 M in 2-methyltetrahydrofuran Green Alternative C3H7ClMg
224391 Propylmagnesium chloride solution 2.0 M in diethyl ether C3H7ClMg
656984 Isopropylmagnesium chloride lithium chloride complex solution 1.3 M in THF C3H7Cl2LiMg
419591 3-Butenylmagnesium bromide solution 0.5 M in THF C4H7BrMg
472611 (1,3-Dioxolan-2-ylmethyl)magnesium bromide solution 0.5 M in THF C4H7BrMgO2
420042 1-Methyl-2-propenylmagnesium chloride solution 0.5 M in THF C4H7ClMg
419583 2-Butenylmagnesium chloride solution 0.5 M in THF C4H7ClMg
419532 2-Methylallylmagnesium chloride solution 0.5 M in THF C4H7ClMg
338257 Isobutylmagnesium bromide solution 2.0 M in diethyl ether C4H9BrMg
529923 Butylmagnesium chloride solution 1.45 M in butyl diglyme C4H9ClMg
224375 Butylmagnesium chloride solution 2.0 M in diethyl ether C4H9ClMg
291005 Butylmagnesium chloride solution 2.0 M in THF C4H9ClMg
225746 Isobutylmagnesium chloride solution 2.0 M in diethyl ether C4H9ClMg
479683 Isobutylmagnesium chloride solution 2.0 M in THF C4H9ClMg
224421 sec-Butylmagnesium chloride solution 2.0 M in diethyl ether C4H9ClMg
224499 tert-Butylmagnesium chloride solution 2.0 M in diethyl ether C4H9ClMg
364649 tert-Butylmagnesium chloride solution 1.0 M in THF C4H9ClMg
773522 tert-Butylmagnesium chloride solution 1.0 M in 2-methyltetrahydrofuran Green Alternative C4H9ClMg
703486 sec-Butylmagnesium chloride lithium chloride complex solution 1.2 M in THF C4H9Cl2LiMg
256021 (Trimethylsilyl)methylmagnesium chloride solution 1.0 M in diethyl ether C4H11ClMgSi
428337 Cyclopentylmagnesium bromide solution 2.0 M in diethyl ether C5H9BrMg
224405 Cyclopentylmagnesium chloride solution 2.0 M in diethyl ether C5H9ClMg
310018 Pentamethylenebis(magnesium bromide) solution 0.5 M in THF C5H10Br2Mg2
732745 2-Pentylmagnesium bromide solution 2 M in diethyl ether C5H11BrMg
675245 3-Pentylmagnesium bromide solution 2.0 M in diethyl ether C5H11BrMg
730580 Isopentylmagnesium bromide solution 2 M in diethyl ether C5H11BrMg
290998 Pentylmagnesium bromide solution 2.0 M in diethyl ether C5H11BrMg
277282 1,1-Dimethylpropylmagnesium chloride solution 1.0 M in diethyl ether C5H11ClMg
550213 2,2-Dimethylpropylmagnesium chloride solution 1.0 M in diethyl ether C5H11ClMg
757969 2,2-Dimethylpropylmagnesium chloride solution 1.0 M in THF C5H11ClMg
732753 2-Methylbutylmagnesium chloride solution 2 M in diethyl ether C5H11ClMg
469033 Pentylmagnesium chloride solution 2.0 M in THF C5H11ClMg
561657 (1,3-Dioxan-2-ylethyl)magnesium bromide solution 0.5 M in THF C6H11BrMgO2
256692 Cyclohexylmagnesium chloride solution 2.0 M in diethyl ether C6H11ClMg
224413 Cyclohexylmagnesium chloride solution 2.0 M in diethyl ether C6H11ClMg
774677 Cyclohexylmagnesium chloride solution 1.0 M in 2-methyltetrahydrofuran Green Alternative C6H11ClMg
752134 Cyclohexylmagnesium chloride solution 1.3 M in THF/toluene (1:1) C6H11ClMg
255025 Hexylmagnesium bromide solution 2.0 M in diethyl ether C6H13BrMg
732761 2-Ethylbutylmagnesium chloride solution 2 M in diethyl ether C6H13ClMg
641626 Hexylmagnesium chloride solution 2.0 M in THF C6H13MgCl
562149 2-Bromobenzylmagnesium bromide solution 0.25 M in diethyl ether C7H6Br2Mg
562130 3-Bromobenzylmagnesium bromide solution 0.25 M in diethyl ether C7H6Br2Mg
563927 4-Fluorobenzylmagnesium chloride 0.25 M in THF C7H6ClFMg
562016 4-Fluorobenzylmagnesium chloride solution 0.25 M in diethyl ether C7H6ClFMg
302759 Benzylmagnesium chloride solution 1.0 M in diethyl ether C7H7ClMg
225916 Benzylmagnesium chloride solution 2.0 M in THF C7H7ClMg
687952 (Cyclohexylmethyl)magnesium bromide solution C7H13BrMg
730599 Cycloheptylmagnesium bromide solution 2 M in diethyl ether C7H13BrMg
550655 Heptylmagnesium bromide solution 1.0 M in diethyl ether C7H15MgBr
562173 2-Methylbenzylmagnesium chloride solution 0.25 M in THF C8H9ClMg
562157 3-Methylbenzylmagnesium chloride solution 0.5 M in THF C8H9ClMg
563773 4-Methylbenzylmagnesium chloride solution 0.5 M in THF C8H9ClMg
424684 Phenethylmagnesium chloride solution 1.0 M in THF C8H9ClMg
562092 2-Methoxybenzylmagnesium chloride solution 0.25 M in THF C8H9ClMgO
562084 3-Methoxybenzylmagnesium chloride solution 0.25 M in THF C8H9ClMgO
562033 4-Methoxybenzylmagnesium chloride solution 0.25 M in THF C8H9ClMgO
630551 (2-Ethylhexyl)magnesium bromide solution 1.0 M in diethyl ether C8H17BrMg
436291 Octylmagnesium bromide solution 2.0 M in diethyl ether C8H17BrMg
324566 Octylmagnesium chloride solution 2.0 M in THF C8H17ClMg
562203 4-Methoxyphenethylmagnesium chloride solution 0.5 M in THF C9H11ClMgO
563811 3,5-Dimethoxybenzylmagnesium chloride solution 0.2 M in THF C9H11ClMgO2
550663 Nonylmagnesium bromide solution 1.0 M in diethyl ether C9H19BrMg
420204 2-Methyl-2-phenylpropylmagnesium chloride solution 0.5 M in diethyl ether C10H13ClMg
637963 3,7-Dimethyloctylmagnesium bromide solution 1.0 M in diethyl ether C10H21BrMg
347108 Decylmagnesium bromide solution 1.0 M in diethyl ether C10H21BrMg
663891 (2-Naphthalenylmethyl)magnesium bromide solution 0.25 M in diethyl ether C11H9BrMg
732737 4-(Benzaldehyde diethylacetal)magnesium bromide solution 1 M in THF C11H15BrMgO2
339628 Dodecylmagnesium bromide solution 1.0 M in diethyl ether C12H25BrMg
337781 Tetradecylmagnesium chloride solution 1.0 M in THF C14H29ClMg
424056 Pentadecylmagnesium bromide solution 0.5 M in diethyl ether C15H31BrMg
394262 Octadecylmagnesium chloride solution 0.5 M in THF C18H37ClMg