Epoxides (oxiranes) have long been recognized as valuable building blocks which allow derivatization either by forming C-X bonds (through reactions with alcohols, ammonia, amines, phenolates, etc.) or by forming new C-C bonds (through reactions with cyanide, malonates, allyl silyl reagents, or metal-organic reagents). Sigma-Aldrich is the exclusive distributor of chiral epoxides manufactured by Rhodia Pharma Solutions, under license, using Jacobsen HKR technology. Additionally, we offer many epoxides from the ChiPros® portfolio.

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ChiPros® Chiral Epoxides
HKR Epoxides
CBHA Ligands

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Molecular Formula

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779202 Ethylene oxide solution 2.5-3.3 M in THF C2H4O
E1012 Epibromohydrin 98% C3H5BrO
45330 (±)-Epichlorohydrin puriss., ≥99.5% (GC) C3H5ClO
45340 (±)-Epichlorohydrin purum, ≥99% (GC) C3H5ClO
E1101 Epifluorohydrin 98% C3H5FO
04704 Glycidamide analytical standard C3H5NO2
110205 (±)-Propylene oxide ReagentPlus®, ≥99% C3H6O
G5809 Glycidol 96% C3H6O2
636185 Ethyl 2,3-epoxypropionate 90% C5H8O3
423955 Methyl 2-methylglycidate 99% C5H8O3
CDS014254 ethyl glycidyl ether AldrichCPR C5H10O2
45380 (±)-Epoxytricarballylic acid monopotassium salt ≥98.0% (NT) C6H5KO7 · H2O
669911 3,4-Epoxy-1-cyclohexene ≥96.0% C6H8O
50062 Glycidyl propargyl ether technical, ≥90% (GC) C6H8O2
757063 (2R,3S)-Dimethyl oxirane-2,3-dicarboxylate 97% C6H8O5
O8704 7-Oxabicyclo[2.2.1]heptane 98% C6H10O
CDS006368 diglycidyl ether AldrichCPR C6H10O3
662100 2,3-Dimethyl-2,3-epoxybutane 99% C6H12O
CDS001448 3,3-Dimethyl-1,2-epoxybutane AldrichCPR C6H12O
151238 Glycidyl methacrylate 97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor C7H10O3
672440 1,2-Epoxycycloheptane 95% C7H12O
639893 Glycidaldehyde diethyl acetal 90% C7H14O3
534749 2-(4-Bromophenyl)oxirane 96% C8H7BrO
534757 2-(4-Chlorophenyl)oxirane 96% C8H7ClO
534765 2-(4-Fluorophenyl)oxirane 95% C8H7FO
471984 9-Oxabicyclo[6.1.0]non-4-ene 95% C8H12O
C110507 Cyclooctene oxide 99% C8H14O
630667 tert-Butyl N-(2-oxiranylmethyl)carbamate 97% C8H15NO3
45364 1,2-Epoxyoctane purum, ≥95.0% (GC) C8H16O
526134 tert-Butyldimethylsilyl glycidyl ether 98% C9H20O2Si
553301 3,4-Epoxy-2-phenyl-1,1,1-trifluoro-2-butanol 95%, mixture of diastereomers C10H9F3O2
469785 Benzyl glycidyl ether 99% C10H12O2
CDS006551 4-isopropenyl-1-methyl-7-oxa-bicyclo[4.1.0]heptane AldrichCPR C10H16O
CDS009915 ethyl 1-oxaspiro[2.5]octane-2-carboxylate AldrichCPR C10H16O3
410829 1,2-Epoxy-9-decene 96% C10H18O
09827 Cyclodecene oxide ≥96.0% (GC) C10H18O
45367 N-(2,3-Epoxypropyl)phthalimide ≥95.0% (GC) C11H9NO3
291404 Ethyl 3-phenylglycidate technical grade, 92%, mixture of cis and trans C11H12O3
CDS000601 13-Oxabicyclo[10.1.0]trideca-4,8-diene AldrichCPR C12H18O
S4921 trans-Stilbene oxide 98% C14H12O
CDS010527 2-(3,4-epoxycyclohexyl)ethyltriethoxysilane AldrichCPR C14H28O4Si
42995 trans-1,3-Diphenyl-2,3-epoxypropan-1-one ≥98.0% C15H12O2
CDS003829 2-biphenylyl glycidyl ether AldrichCPR C15H14O2
11070 Aromadendrene oxide 2 ≥95.0% C15H24O
CDS000487 2-Hexadecyloxirane AldrichCPR C18H36O
73417 Bisphenol A (2,3-dihydroxypropyl) glycidyl ether analytical standard C21H26O5
412848 Dodecyl and tetradecyl glycidyl ethers technical grade