Organotin
Organotin compounds have classically been one of the more utilized synthons in palladium-catalyzed cross coupling reactions. Since the first report by Stille in 1977, numerous applications of organotin reagents have found to be commonplace in the formation of new C-C bonds in the synthesis of natural products and other small molecules for drug discovery. Sigma-Aldrich also offers an extensive portfolio of organoditin and organotin hydride reagents for the generation of Stille Coupling precursors to obtain more complex coupling partners and dehalogenation reactions to afford hydrocarbons in late-stage synthetic sequences.

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Heterocyclic Organotin Reagents for Stille Coupling

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CDS001577 Tin(II) pyrophosphate AldrichCPR Organotins
 O7P2Sn2
    • 288039 Methyltin trichloride 97% Organotin Halides
    		 CH3Cl3Sn
    • 288012 Dimethyltin dichloride 97% Organotin Halides
    		 C2H6Cl2Sn
    • 748382 Dimethyltin oxide Organotin Oxides
    		 C2H6OSn
    • 257915 Trimethyltin bromide 95% Organotin Halides
    		 C3H9BrSn
    • 146498 Trimethyltin chloride Organotin Halides
    		 C3H9ClSn
    • 375195 Trimethyltin chloride solution 1.0 M in THF Organotin Halides
    		 C3H9ClSn
    • 375187 Trimethyltin chloride solution 1.0 M in hexanes Organotin Halides
    		 C3H9ClSn
    • 349488 Azidotrimethyltin(IV) 97% Organotins
    		 C3H11N3Sn
    • 201057 Butyltin trichloride 95% Organotin Halides
    		 C4H9Cl3Sn
    • 344931 Butyltin hydroxide oxide hydrate 97% Organotin Oxides
    		 C4H10O2Sn · xH2O
    • 344923 Butyltin chloride dihydroxide 96% Organotin Halides
    		 C4H11ClO2Sn
    • 481394 Tetramethyltin 95% Green Alternative Organotins
    		 C4H12Sn
    • 429287 (Dimethylamino)trimethyltin(IV) technical grade Organotins
    		 C5H15NSn
    • 277231 Phenyltin trichloride 98% Organotin Halides
    		 C6H5Cl3Sn
    • 288047 Triethyltin bromide 97% Organotin Halides
    		 C6H15BrSn
    • 288020 Hexamethylditin 99% Organoditins
    		 C6H18Sn2
    • 328669 Tetravinyltin 97% Organotins
    		 C8H12Sn
    • 278009 Di-tert-butyltin dichloride 98% Organotin Halides
    		 C8H18Cl2Sn
    • 205494 Dibutyltin dichloride 96% Organotin Halides
    		 C8H18Cl2Sn
    • 183083 Dibutyltin(IV) oxide 98% Organotin Oxides
    		 C8H18OSn
    • 34980 Dibutyltin(IV) oxide purum Organotin Oxides
    		 C8H18OSn
    • 483613 Bis(trimethylstannyl)acetylene Organotins
    		 C8H18Sn2
    • 366331 Trimethyl(phenyl)tin 98% Organotins
    		 C9H14Sn
    • 725374 2,2-Dibutyl-[1,3,2]dioxastannolane 96% Organotin Oxides
    		 C10H22O2Sn
    • 429953 Trimethyl(phenylethynyl)tin 97% Organotins
    		 C11H14Sn
    • 229202 Diphenyltin dichloride 96% Organotin Halides
    		 C12H10Cl2Sn
    • 479462 Diphenyltin(IV) oxide 97% Organotin Oxides
    		 C12H10OSn
    • 440477 Dibutyltin maleate 95% Organotins
    		 C12H20O4Sn
    • 271446 Tetraallyltin 97% Organotins
    		 C12H20Sn
    • 290890 Dibutyltin diacetate technical grade Organotins
    		 C12H24O4Sn
    • T50202 Tributyltin chloride 96% Organotin Halides
    		 C12H27ClSn
    • 615633 Tributyltin chloride-d27 98 atom % D, 96% (CP) Organotin Halides
    		 C12D27ClSn
    • 333034 Tributyltin iodide technical grade, 90% Organotin Halides
    		 C12H27ISn
    • 234788 Tributyltin hydride contains 0.05% BHT as stabilizer, 97% Organotins
    		 C12H28Sn
    • 366420 Tributylstannyl trifluoromethanesulfonate 90% Organotins
    		 C13H27F3O3SSn
    • 530786 Tributyltin isocyanate Organotins
    		 C13H27NOSn
    • 229245 Tributyltin methoxide 97% Organotins
    		 C13H30OSn
    • 711063 Tributyl(perfluoroethyl)stannane 97% Organotins
    		 C14H27F5Sn
    • 275069 Ethynyltributylstannane 95% Organotins
    		 C14H28Sn
    • 95085 Tributyl(vinyl)stannane purum, ≥97.0% (GC) Organotins
    		 C14H30Sn
    • 271438 Tributyl(vinyl)tin 97% Organotins
    		 C14H30Sn
    • 251518 Tributyltin ethoxide 97% Organotins
    		 C14H32OSn
    • SYX00076 1-Tributylstannyl-3,3,3-trifluoro-1-propyne AldrichCPR Organotins
    		 C15H27F3Sn
    • 706965 4-Bromo-2-(tributylstannyl)thiazole Organotins
    		 C15H28BrNSSn
    • 728896 2-Chloro-5-(tributylstannyl)thiazole 96% Organotins
    		 C15H28ClNSSn
    • 638617 2-(Tri-n-butylstannyl)oxazole Organotins
    		 C15H29NOSn
    • 642541 2-Tributylstannylthiazole 97% Organotins
    		 C15H29NSSn
    • 499862 Tributyl(1-propynyl)tin 95% Organotins
    		 C15H30Sn
    • SYX00013 2-(Tributylstannyl)propene AldrichCPR Organotins
    		 C15H32Sn
    • 271411 Allyltributylstannane 97% Organotins
    		 C15H32Sn
    • SYX00083 Cyclopropyltributylstannane AldrichCPR Organotins
    		 C15H32Sn
    • SYX00050 Tributyl[(methoxymethoxy)methyl]stannane AldrichCPR Organotins
    		 C15H34O2Sn
    • 367265 Trimethyl(tributylstannyl)silane 97% Organotins
    		 C15H36SiSn
    • 706868 2-Chloro-5-(tributylstannyl)pyrimidine 95% Organotins
    		 C16H29ClN2Sn
    • 675660 2-(Tributylstannyl)pyrazine 95% Organotins
    		 C16H30N2Sn
    • 721174 2-(Tributylstannyl)pyrimidine 95% Organotins
    		 C16H30N2Sn
    • 719730 5-(Tributylstannyl)pyrimidine 95% Organotins
    		 C16H30N2Sn
    • 414506 2-(Tributylstannyl)furan 97% Organotins
    		 C16H30OSn
    • 414492 2-(Tributylstannyl)thiophene 97% Organotins
    		 C16H30SSn
    • 707813 1-Methyl-4-(tributylstannyl)-1H-pyrazole 97% Organotins
    		 C16H32N2Sn
    • 739499 1-Methyl-5-(tributylstannyl)-1H-pyrazole 97% Organotins
    		 C16H32N2Sn
    • 718793 1-Methyl-5-(tributylstannyl)imidazole 95% Organotins
    		 C16H32N2Sn
    • 719501 N-Methyl-4-(tributylstannyl)imidazole 95% Organotins
    		 C16H32N2Sn
    • 734055 Tributyl(4,5-dihydrofuran-2-yl)stannane 97% Organotins
    		 C16H32OSn
    • 707937 cis-Tributyl[2-ethoxyethenyl]stannane 97% Organotins
    		 C16H34OSn
    • 275123 Tributyl(1-ethoxyvinyl)tin 97% Organotins
    		 C16H34OSn
    • 331090 Bis(dibutylchlorotin(IV)) oxide 98% Organotin Halides
    		 C16H36Cl2OSn2
    • T6008 Tetrabutyltin technical grade, 93% Organotins
    		 C16H36Sn
    • 704849 2-Bromo-5-(tributylstannyl)pyridine 97% (H-NMR) Organotins
    		 C17H30BrNSn
    • 704865 2-Bromo-6-(tributylstannyl)pyridine 97% (H-NMR) Organotins
    		 C17H30BrNSn
    • 704830 5-Bromo-2-(tributylstannyl)pyridine 97% (H-NMR) Organotins
    		 C17H30BrNSn
    • 719609 2-Chloro-6-(tributylstannyl)pyridine Organotins
    		 C17H30ClNSn
    • 696692 2-Fluoro-3-(tributylstannyl)pyridine 97% Organotins
    		 C17H30FNSn
    • 719315 2-Fluoro-4-(tributylstannyl)pyridine Organotins
    		 C17H30FNSn
    • 678333 2-(Tributylstannyl)pyridine 85% Organotins
    		 C17H31NSn
    • 698598 3-(Tributylstannyl)pyridine 97% Organotins
    		 C17H31NSn
    • 731684 2-(Tributylstannyl)-3-methoxypyrazine 97% Organotins
    		 C17H32N2OSn
    • 707031 6-Methoxy-2-(tributylstannyl)pyrimidine 95% Organotins
    		 C17H32N2OSn
    • 675679 1-Methyl-2-(tributylstannyl)pyrrole 95% Organotins
    		 C17H33NSn
    • 734063 Tributyl(5,6-dihydro-4H-pyran-2-yl)stannane Organotins
    		 C17H34OSn
    • 615625 Triphenyl-d15-tin chloride ≥98 atom % D Organotin Halides
    		 C18D15ClSn
    • 348104 Triphenyltin hydroxide Organotins
    		 C18H16OSn
    • 244775 Triphenyltin hydride Organotins
    		 C18H16Sn
    • 721158 Tributyl(4-chloro)phenylstannane 95% Organotins
    		 C18H31ClSn
    • 520586 Dibutyltin bis(acetylacetonate) 95% Organotins
    		 C18H32O4Sn
    • 374601 Tributylphenylstannane 97% Organotins
    		 C18H32Sn
    • 480827 Tricyclohexyltin chloride 95% Organotin Halides
    		 C18H33ClSn
    • 721115 2-methoxy-6-(tributylstannyl)pyridine 96% Organotins
    		 C18H33NOSn
    • 706981 Ethyl-5-(tributylstannyl)isoxazole-3-carboxylate Organotins
    		 C18H33NO3Sn
    • 721220 2-Methyl-6-(tributylstannyl)pyridine Organotins
    		 C18H33NSn
    • 739782 5-Methyl-2-(tributylstannyl)pyridine 95% Organotins
    		 C18H33NSn
    • SYX00093 Tributyl[2,2-difluoro-1-(2-methoxyethoxymethoxy)vinyl]stannane AldrichCPR Organotins
    		 C18H36F2O3Sn
    • 773654 1,3,5-Trimethyl-4-(tributylstannyl)-1H-pyrazole 97% Organotins
    		 C18H36N2Sn
    • 683930 2-Tributylstannylbenzo[b]thiophene 95% Organotins
    		 C20H32SSn
    • 340359 Tributyl(phenylethynyl)tin 95% Organotins
    		 C20H32Sn
    • 729256 2-(N-Boc-amino)-5-(tributylstannyl)thiazole Organotins
    		 C20H38N2O2SSn
    • 176214 1,3-Diacetoxy-1,1,3,3-tetrabutyldistannoxane 97% Organotin Oxides
    		 C20H42O5Sn2
    • 332364 Allyltriphenylstannane 97% Organotins
    		 C21H20Sn
    • 719366 N-Methyl-2-(tributylstannyl)indole 97% Organotins
    		 C21H35NSn
    • 721212 4-(4-(Tributylstannyl)phenyl)morpholine Organoditins
    Organotins
    		 C22H39NOSn
    • T26727 Tetraphenyltin 97% Organotins
    		 C24H20Sn
    • 720585 Bis(tributyltin)sulfide 97% Organotins
    		 C24H54SSn2
    • 251127 Bis(tributyltin) 95% Organoditins
    		 C24H54Sn2
    • 721131 (4-Benzyloxyphenyl)tributylstannane Organotins
    		 C25H38OSn
    • 271403 Bis(tributylstannyl)acetylene 95% Organotins
    		 C26H54Sn2
    • 731625 trans-1,2-Bis(tributylstannyl)ethene 97% Organotins
    		 C26H56Sn2
    • 717703 2,5-Bis(tributylstannyl)thiophene 97% Organotins
    		 C28H56SSn2
    • 721204 1,4-Bis(tributylstannyl)benzene Organotins
    		 C30H58Sn2
    • 717614 5,5′-Bis(tributylstannyl)-2,2′-bithiophene 97% Organotins
    		 C32H58S2Sn2
    • 291234 Dibutyltin dilaurate 95% Organotins
    		 C32H64O4Sn