Nickel Catalysts
Nickel catalysis plays a central role in many synthetic transformations ranging from cross coupling reactions in which carbon-carbon bonds are formed to the reduction of electron rich carbon bonds with raney nickel catalysts. Sigma-Aldrich provides an extensive suite of such nickel catalysts. These nickel catalysts span a range of oxidation states: Nickel (0), nickel (II), nickel (III) and nickel (IV). The types of Ni catalysts available for immediate purchase are aluminum nickel (Al Ni) alloys, ammonium nickel hydrates, Ni COD, Ni halides (chlorides, bromides, fluorides and iodides), Ni cyclopentadienyls, nickel metal, nickel acacs, and Raney Nickel catalysts that are products of W.R. Grace and Company.

Regardless of the application, there is an extensive and high-purity selection of Ni catalysts available in the Sigma-Aldrich product portfolio.

Product #

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Description

Molecular Formula

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524271 Allyl(cyclopentadienyl)nickel(II) 97% C8H10Ni
    • 72240 Aluminum-nickel alloy purum, 50% Al basis, 50% Ni basis  
    • 221651 Aluminum-nickel catalyst Al-Ni 50:50 wt. % AlNi
    • A1827 Ammonium nickel(II) sulfate hexahydrate ≥98% H8N2NiO8S2 · 6H2O
    • 574988 Ammonium nickel(II) sulfate hexahydrate 99.999% trace metals basis H8N2NiO8S2 · 6H2O
    • 09885 Ammonium nickel(II) sulfate hexahydrate purum p.a., ≥98.0% (KT) H8N2NiO8S2 · 6H2O
    • 244988 Bis(1,5-cyclooctadiene)nickel(0) C16H24Ni
    • N7524 Bis(cyclopentadienyl)nickel(II) C10H10Ni
    • 901116 trans-Bis(dicyclohexylphenylphosphine)(2-methylphenyl)nickel(II) chloride C43H61ClNiP2
    • 728551 Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride ≥97% (AT) C16H20ClN3Ni
    • 901166 cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride C51H39ClNiP2
    • 328219 [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II) C26H24Cl2NiP2
    • 901162 cis-[1,2-Bis(diphenylphosphino)ethane](2-methylphenyl)nickel(II) chloride ≥95% C33H31ClNiP2
    • 470554 [1,1′-Bis(diphenylphosphino)ferrocene]dichloronickel(II) 97% C34H28Cl2FeNiP2
    • 335363 [1,3-Bis(diphenylphosphino)propane]dichloronickel(II) C27H26Cl2NiP2
    • 510475 Bis(methylcyclopentadienyl)nickel(II) 97% C12H14Ni
    • 901169 trans-Bis(methyldiphenylphosphine)(2-methylphenyl)nickel(II) chloride C33H33ClNiP2
    • 904937 2,6-Bis(N-pyrazolyl)pyridine nickel (II) dichloride ≥95% anhydrous basis C11H9Cl2N5Ni
    • 901165 trans-Bis(tricyclohexylphosphine)(2-methylphenyl)nickel(II) chloride ≥95% C43H73ClNiP2
    • 708526 Bis(tricyclohexylphosphine)nickel(II) dichloride 97% C36H66Cl2NiP2
    • 901117 trans-Bis(tricyclopentylphosphine)(2-methylphenyl)nickel(II) chloride C37H61ClNiP2
    • 901163 trans-Bis(triethylphosphine)(2,4,6-trimethylphenyl)nickel(II) bromide ≥95% C21H41BrNiP2
    • 213934 Bis(triphenylphosphine)dicarbonylnickel C38H30NiO2P2
    • 237116 Bis(triphenylphosphine)nickel(II) dichloride synthesis grade C36H30Cl2NiP2
    • 900941 Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II) ≥95% C39H42ClF2FeNNiP2
    • 900943 Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine]nickel(II) C43H60ClFeNNiP2
    • 900942 Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine]nickel(II) ≥95% C43H48ClFeNNiP2
    • 900944 Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II) ≥95% C39H44ClFeNNiP2
    • 512516 Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II) 97% C23H20ClNiP
    • 794279 Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II) C43H37ClNiP2
    • 767662 Chloro(1-naphthyl)bis(triphenylphosphine)nickel(II) 97% C46H37ClNiP2
    • 908886 N-Cyano-4-methoxy-picolinimidamide ≥95% C8H8N4O
    • 911402 (CyPAd-DalPhos)NiCl(otol) ≥95% C35H49ClNiO3P2
    • 331708 Dibromobis(triphenylphosphine)nickel(II) 99% C36H30Br2NiP2
    • 761273 Dichloro[1,2-bis(diethylphosphino)ethane]nickel(II) 97% C10H24Cl2NiP2
    • 332062 Dichlorobis(tributylphosphine)nickel(II) C24H54Cl2NiP2
    • 567671 Dichlorobis(trimethylphosphine)nickel(II) 97% C6H18Cl2NiP2
    • 422592 Dilithium tetrabromonickelate(II) solution 0.5 M in THF Br4Li2Ni
    • 901742 Dimethyl[(1-pyrrolidinyl)phenyl]-amine nickel(II) chloride ≥95% C18H22ClN3Ni
    • 802948 (dppf)Ni(o-tolyl)Cl C41H35ClFeNiP2
    • 804371 Fro-DO, mixture of diastereomers 97% C24H22N2O6S2
    • 677426   Iron-nickel alloy nanopowder, <100 nm particle size (BET), ≥97%  
    • 902039 4-Methoxypicolinimidamide hydrochloride ≥95% C7H10ClN3O
    • 902063 (2Z,6Z)-N′2,N′6-Dicyanopyridine-2,6-bis(carboximidamide) C9H7N7
    • ALD00608 Ni(bpy)3Br2 C30H24Br2N6Ni
    • 268259 Nickel foil, thickness 0.125 mm, ≥99.9% Ni
    • 357626 Nickel wire, diam. 0.5 mm, ≥99.9% trace metals basis Ni
    • 357634 Nickel wire, diam. 0.25 mm, ≥99.9% Ni
    • 208779 Nickel on silica/alumina extent of labeling: ~65 wt. % loading, powder Green Alternative  
    • 244066 Nickel(II) acetate tetrahydrate 98% C4H6NiO4 · 4H2O
    • 72225 Nickel(II) acetate tetrahydrate purum p.a., ≥99.0% (KT) C4H6NiO4 · 4H2O
    • 283657 Nickel(II) acetylacetonate 95% C10H14NiO4
    • 776254 Nickel(II) bis(trifluoromethanesulfonimide) hydrate 95% C4F12N2NiO8S4 · xH2O
    • 217891 Nickel(II) bromide 98% Br2Ni
    • 233730 Nickel(II) bromide hydrate 98% Br2Ni · xH2O
    • 72243 Nickel(II) bromide trihydrate 98% (AT) Br2Ni · 3H2O
    • 406341 Nickel(II) bromide ethylene glycol dimethyl ether complex 97% C4H10Br2NiO2
    • 459674 Nickel(II) bromide 2-methoxyethyl ether complex C6H14Br2NiO3
    • 544183 Nickel carbonate, basic hydrate 99.9% trace metals basis CH4Ni3O7 · xH2O
    • 72248 Nickel(II) carbonate basic hydrate technical, ~46% Ni basis (KT)  
    • 339350 Nickel(II) chloride 98% Cl2Ni
    • 31462 Nickel(II) chloride hexahydrate puriss. p.a., ≥98% Cl2Ni · 6H2O
    • 364304 Nickel(II) chloride hydrate 99.95% trace metals basis Cl2Ni · xH2O
    • 696668 Nickel(II) chloride ethylene glycol dimethyl ether complex 98% C4H10O2 · Cl2Ni
    • 342211 Nickel(II) fluoride F2Ni
    • 339709 Nickel(II) hexafluoroacetylacetonate hydrate 98% C10H2F12NiO4 · xH2O
    • 400777 Nickel(II) iodide powder I2Ni
    • 244074 Nickel(II) nitrate hexahydrate crystals or chunks N2NiO6 · 6H2O
    • 408883 Nickel(II) 1,4,8,11,15,18,22,25-octabutoxy-29H,31H-phthalocyanine Dye content 97 % C64H80N8NiO8
    • 72262 Nickel peroxide technical, oxidizing agent, ~30% active peroxide basis NiO2
    • 367192 Nickel(II) peroxide hydrate Green Alternative NiO2 · xH2O
    • 372641 Nickel phosphide −100 mesh, 98% Ni2P
    • 274909 Nickel(II) phthalocyanine-tetrasulfonic acid tetrasodium salt C32H12N8Na4NiO12S4
    • 227676 Nickel(II) sulfate hexahydrate ACS reagent, ≥98% NiO4S · 6H2O
    • 13635 Nickel(II) sulfate hexa-/ heptahydrate for nickel plating, DIN 50970 H, ≥20.6% Ni and Co basis NiO4S · xH2O
    • 343226 Nickel sulfide 99.7% trace metals basis, −150 mesh Green Alternative Ni3S2
    • 731331 Nickel(II) trifluoromethanesulfonate 96% C2F6NiO6S2
    • 269948 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine nickel(II) 97% C36H44N4Ni
    • 390011 Potassium hexafluoronickelate(IV) 99% F6K2Ni
    • 415154 Potassium tetracyanonickelate(II) hydrate C4K2N4Ni · xH2O
    • 902047 Pyridine-2,6-bis(carboximidamide) dihydrochloride ≥95% C7H11Cl2N5
    • 221678 Raney®-Nickel W.R. Grace and Co. Raney®
    2800, slurry, in H2O, active catalyst     		 
    • 510041 Raney®-Nickel W.R. Grace and Co. Raney®
    4200, slurry, in H2O, active catalyst     		 
    • 510033 Raney®-Nickel W.R. Grace and Co. Raney®
    2400, slurry, in H2O, active catalyst     		 
    • 510068 Raney®-Nickel W.R. Grace and Co. Raney®
    3202, slurry, in H2O, active catalyst     		 
    • 244996 Tetrakis(triphenylphosphine)nickel(0) Ni 4-7 % (approx.) C72H60NiP4
    • 288063 Tetrakis(triphenylphosphite)nickel(0) C72H64NiO12P4
    • 252204 5,10,15,20-Tetraphenyl-21H,23H-porphine nickel(II) dye content ≥95 % C44H28N4Ni
    • 798975 Trovitch Ni-Precatalyst C34H38N2NiP2