Pyrroles

Pyrroles (1H-pyrroles) are heterocyclic aromatic compounds consisting of a five-membered ring containing a nitrogen atom. Pyrroles are important synthons in the synthesis of natural products. They exhibit remarkable biological properties such as hypolipidemic, antimicrobial, anti-inflammatory and antitumour activities and are able to inhibit retroviral reverse transcriptases [i.e., human immunodeficiency virus type 1 (HIV-1)], cellular DNA polymerases and protein kinases. Furthermore, some of these compounds are useful intermediates in the synthesis of biologically important naturally occurring alkaloids and unnatural heterocyclic derivatives. Phosphino-substituted N-aryl pyrroles, a novel class of sterically demanding and electron rich biaryl phosphine ligands, exhibit high turnover rates and low catalyst loadings. The presence of a halogen allows these reagents to be used as substrates in various coupling reactions, including Suzuki-Miyaura cross-coupling reactions.

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Acetylenic Schmidt Reaction
Intermolecular Hydroamination
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(2-Trimethylsilyl)-ethanesulfonyl Reagents
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CBR01780 4-Bromo-1H-pyrrole-2-carbonitrile AldrichCPR C5H3BrN2
CDS011876 4-Chloro-1H-pyrrole-2-carboxylic acid AldrichCPR C5H4ClNO2
395137 2-(Trichloroacetyl)pyrrole 99% C6H4Cl3NO
CBR01807 4-Bromo-1-methyl-1H-pyrrole-2-carbonitrile AldrichCPR C6H5BrN2
CBR01751 4-Bromo-5-methyl-1H-pyrrole-2-carbonitrile AldrichCPR C6H5BrN2
CDS015687 4H-thieno[3,2-b]pyrrole-5-carbonyl chloride AldrichCPR C7H4ClNOS
CDS019587 4-Bromo-5-formyl-1-methyl-1H-pyrrole-2-carboxylic acid AldrichCPR C7H6BrNO3
CBR01756 4-Bromo-1,5-dimethyl-1H-pyrrole-2-carbonitrile AldrichCPR C7H7BrN2
CBR01774 4-Bromo-1-ethyl-1H-pyrrole-2-carbonitrile AldrichCPR C7H7BrN2
CBR01832 4-Bromo-5-ethyl-1H-pyrrole-2-carbonitrile AldrichCPR C7H7BrN2
729787 Ethyl 4-bromopyrrole-2-carboxylate 97% C7H8BrNO2
ANV00082 Methyl 4-bromo-1-methyl-1H-pyrrole-2-carboxylate AldrichCPR C7H8BrNO2
CDS000004 1-(3-Bromopropyl)-1H-pyrrole AldrichCPR C7H10BrN
ANV00044 Methyl 4-amino-1-methyl-1H-pyrrole-2-carboxylate hydrochloride AldrichCPR C7H11ClN2O2
CDS014399 Ethyl 4-bromo-3,5-dimethyl-1H-pyrrole-2-carboxylate AldrichCPR C9H12BrNO2
CDS017800 N-Methyl-N-[(4-methyl-4H-thieno[3,2-b]pyrrol-5-yl)methyl]amine hydrochloride AldrichCPR C9H13ClN2S
CDS016952 1-(3-bromophenyl)-1H-pyrrole AldrichCPR C10H8BrN
452947 1-(4-Chlorophenyl)-1H-pyrrole 97% C10H8ClN
CDS014472 1-(4-iodophenyl)pyrrole AldrichCPR C10H8IN
CDS004927 N-(2-cyano-3-fluorophenyl)pyrrole AldrichCPR C11H7FN2
CDS017416 1-(4-chlorophenyl)-1H-pyrrole-2-carbaldehyde AldrichCPR C11H8ClNO
CDS017043 2-chloro-5-pyrrol-1-yl-benzoic acid AldrichCPR C11H8ClNO2
CDS006962 4-Chloro-3-(1H-pyrrol-1-yl)benzoic acid AldrichCPR C11H8ClNO2
CDS002041 5-(4-Chlorophenyl)-1H-pyrrole-2-carboxylic acid AldrichCPR C11H8ClNO2
CDS011768 (3-Fluoro-phenyl)-(1H-pyrrol-3-yl)-methanone AldrichCPR C11H8FNO
CDS007385 1-(3-Fluoro-phenyl)-1H-pyrrole-2-carbaldehyde AldrichCPR C11H8FNO
CDS014331 1-[3-(Bromomethyl)phenyl]-1H-pyrrole AldrichCPR C11H10BrN
CDS001952 1-(3,4-Dichlorobenzyl)-1H-pyrrole-2-carbaldehyde AldrichCPR C12H9Cl2NO
CDS005664 5-(4-Chlorophenyl)-1-methyl-1H-pyrrole-2-carbaldehyde AldrichCPR C12H10ClNO
CDS011493 1-(3-Fluorophenyl)-2,5-dimethyl-1H-pyrrole-3-carbaldehyde AldrichCPR C13H12FNO
CDS014795 1-(4-fluoro-phenyl)-2,5-dimethyl-1H-pyrrole-3-carboxylic acid AldrichCPR C13H12FNO2
CDS002424 3-[5-(4-Fluorophenyl)-1H-pyrrol-2-yl]propanoic acid AldrichCPR C13H12FNO2
709808 3-Bromo-1(triisopropysilyl)pyrrole 97% C13H24BrNSi
CDS020482 1-(4-Fluorophenyl)-5-(1H-pyrrol-1-yl)-1H-pyrazole-4-carboxylic acid AldrichCPR C14H10FN3O2
CDS016873 4-(2,4-dichlorobenzoyl)-N-(2-hydroxyethyl)-1H-pyrrole-2-carboxamide AldrichCPR C14H12Cl2N2O3