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        胡金波教授

胡金波教授实验室的主要研究方向包括开发新的氟化试剂和反应,尤其是二氟甲基化、二氟亚甲基化和单氟甲基化方法。在过去十年中,他的团队开发的氟烷基砜、磺酰亚胺和硅烷都是强大的氟烷基化试剂。此外,他们还开发了数种用户友好型的二氟卡宾试剂,如TMSCF3/NaI、TMSCF2Cl/Cl-和TMSCF2Br/Br-系统。目前,他的实验室还专注于新型试剂和碳氟键形成反应的开发。

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胡金波实验室最近发表的文章:

Yanchuan Zhao, Weizhou Huang, Ji Zheng, Jinbo Hu
Organic Letters 2011-10-07
Since 1995, Me(3)SiCF(2)H has been widely believed to be an inefficient difluoromethylating agent, which requires harsh reaction conditions to cleave its rather inert Si-CF(2)H bond. However, it has now been found that, by using a proper Lewis base activator, Me(3)SiCF(2)H can efficiently difluoromethylate various aldehydes, ket...Read More
Hongchao Zheng, Sina Ghanbari, Shinji Nakamura, Dennis G Hall
Angewandte Chemie. International edition in English 2012-06-18
Mingyou Hu, Zhengbiao He, Bing Gao, Lingchun Li, Chuanfa Ni, Jinbo Hu
Journal of the American Chemical Society 2013-11-20
A novel Cu-catalyzed gem-difluoroolefination of diazo compounds is described. This transformation starts from readily available TMSCF3 and diazo compounds, via trifluoromethylation followed by C-F bond cleavage, to afford the desired 1,1-difluoroalkene products.Read More