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Seth Herzon教授

Herzon研究小组已经开发出了数种高活性催化剂,用于反Markovnikov水合和末端炔 烃还原水合,以分别形成醛和直链醇。还原水合反应通过形成醛中间体来进行原位 还原。催化剂794120794139,以及配体和催化剂L511692的干燥混合物对空气和 湿气都具有稳定性。所有反应都应在脱氧溶剂中进行。

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Herzon 实验室最近发表的文章:  

Le Li, Seth B Herzon
Nature Chemistry 2014-01-01
There is currently great interest in the development of multistep catalytic processes in which one or several catalysts act sequentially to rapidly build complex molecular structures...Read More
Le Li, Mingshuo Zeng, Seth B Herzon
Angewandte Chemie (International Edition) 2014-07-21
Anti-Markovnikov alkyne hydration provides a valuable route to aldehydes. Half-sandwich ruthenium complexes ligated by 5,5'-bis(trifluoromethyl)-2,2'-bipyridine are remarkably active for this transformation...Read More
Mingshuo Zeng, Le Li, Seth B Herzon
Journal of the American Chemical Society 2014-05-14
The conversion of terminal alkynes to functionalized products by the direct addition of heteroatom-based nucleophiles is an important aim in catalysis. We report the design, synthesis, and mechanistic studies of the half-sandwich ruthenium complex 12, which is a highly active catalyst for the anti-Markovnikov reductive hydration of alkynes...Read More