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Cross-Coupling Reactions in Water

As the chemistry world shifts toward a more sustainable perspective on synthesis, legendary chemist Barry Sharpless continues to innovate the field. This time, the topic is developing a green, organic solvent-free catalytic system for Suzuki cross-coupling reaction. Although this issue of aqueous cross-coupling reactions has been addressed, the addition of PEGs and harsh conditions are often still required. Luckily, Nobel Laureate Barry Sharpless and his lab group have developed this aryl flurosulfate (ALD00428) to remedy these problems and provide excellent yields!

……………View Details for Aldrich Product No. ALD00428 4,4′-Dihydroxydiphenyl sulfone bisfluorosulfinate .................. View Details for Aldrich Product No. 900285 MCAT-53<SUP>™</SUP>
But wait, he is not alone! Researchers at Chicago Discovery Services have developed a ruthenium catalyst to run coupling reactions in water using their novel catalyst MCAT-53. At the same time, Bruce Lipshutz and his research group are continuing to grow their library of water stable, room temperature cross-coupling reagents with HandaPhos, which works in tandem with Nok for biaryl coupling.

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