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393541

Gallium(III) acetylacetonate

99.99% trace metals basis

Sinónimos:

Ga(acac)3, Gallium(III) 2,4-pentanedionate

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A ustedes/SKUDisponibilidadPrecio
5 g
Comprobar disponibilidad del carrito
US$ 238,00
25 g
Comprobar disponibilidad del carrito
US$ 1.060,00

Acerca de este artículo

Fórmula lineal:
[CH3COCH=C(O-)CH3]3Ga
Número CAS:
Peso molecular:
367.05
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
238-377-0
MDL number:

US$ 238,00

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Quality Segment

assay

99.99% trace metals basis

form

solid

reaction suitability

core: gallium, reagent type: catalyst

mp

196-198 °C (dec.) (lit.)

SMILES string

CC(=O)\C=C(\C)O[Ga](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Ga/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

ZVYYAYJIGYODSD-LNTINUHCSA-K

General description

Gallium(III) acetylacetonate is a white to off-white crystalline solid with purity (99.99% trace metals basis) widely used as a precursor for thin films and nanomaterials. It is soluble in organic solvents such as ethanol, acetone, and toluene, making it suitable for solution-based nanoparticle synthesis. Its thermal stability, with decomposition occurring above ~200 °C, allows for controlled gallium release, making it ideal for the synthesis of nanomaterials and oxide layers. It is commonly employed in metal-organic chemical vapor deposition (CVD) and atomic layer deposition (ALD) to produce gallium oxide (Ga₂O₃) and gallium nitride (GaN) thin films, which are essential for electronic and optoelectronic applications.

Application

Gallium(III) acetylacetonate can be used:
  • As a precursor to synthesize nanocrystalline gallium oxide spinels via solvothermal process for various applications like photocatalysis, battery cathode materials and electrocatalysis.
  • To fabricate LiGa alloy layer on Li metal anode from in-situ electroreduction. It suppresses the anode dendrite formation in lithium-sulfur batteries.
  • To prepare highly efficient gallium-platinum (GaPt3) nanoparticles hot-solvent synthesis which act as electrocatalysts for hydrogen evolution reaction.
  • To synthesize γ-Ga2O3 nanocrystals for fabricating electron-transporting layer for perovskite solar cells. It forms effective interfacial connections with the perovskite top layer, enhancing the efficiency of charge transport.

Features and Benefits

  • The high purity (99.99% trace metals basis) ensures that no impurities interfere with the synthesis process, leading to higher yields and better quality of the gallium compounds.
  • High purity enhances catalytic activity and selectivity, reducing the formation of by-products and improving overall reaction efficiency.
  • The absence of trace metal impurities ensures the integrity and performance of the thin films, resulting in improved device efficiency and longevity of optoelectronic devices.
  • The high purity of the precursor minimizes defects and impurities in the semiconductor materials, enhancing their electrical properties and performance.

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Este artículo
331716494534I3300
form

solid

form

powder, solid

form

granular, powder or crystals

form

powder or solid (or crystals)

assay

99.99% trace metals basis

assay

99.9% trace metals basis

assay

99.99% trace metals basis

assay

≥99.99% trace metals basis

mp

196-198 °C (dec.) (lit.)

mp

143 °C (dec.) (lit.)

mp

210-213 °C (lit.)

mp

187-189 °C (lit.)

Quality Level

100

Quality Level

100

Quality Level

-

Quality Level

100

reaction suitability

core: gallium, reagent type: catalyst

reaction suitability

core: gadolinium, reagent type: catalyst

reaction suitability

core: cobalt

reaction suitability

core: indium, reagent type: catalyst


pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Clase de almacenamiento

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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