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762385

6,6′-Bis(4-(S)-isopropyl-2-oxazolinyl)-2,2′-bipyridine

96%, solid

Synonym(s):

Bipymox

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Size/SKUAvailabilityPrice
1 g
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CHF 303.00

About This Item

Empirical Formula (Hill Notation):
C22H26N4O2
CAS Number:
Molecular Weight:
378.47
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:

CHF 303.00


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Product Name

6,6′-Bis(4-(S)-isopropyl-2-oxazolinyl)-2,2′-bipyridine, 96%

Quality Segment

assay

96%

form

solid

optical activity

[α]/D -97.0°, c = 0.5% in dichloromethane

reaction suitability

reaction type: Asymmetric synthesis, reagent type: ligand
reaction type: Hydrosilylations

mp

185-190 °C

SMILES string

CC(C)[C@H]1COC(=N1)c2cccc(n2)-c3cccc(n3)C4=N[C@H](CO4)C(C)C

InChI

1S/C22H26N4O2/c1-13(2)19-11-27-21(25-19)17-9-5-7-15(23-17)16-8-6-10-18(24-16)22-26-20(12-28-22)14(3)4/h5-10,13-14,19-20H,11-12H2,1-4H3/t19-,20-/m1/s1

InChI key

NNCROLGXDLXLJM-WOJBJXKFSA-N

Application

Ligand used in the asymmetric hydrosilation of ketones.

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This Item
675806671584905240
description

96%

description

97%

description

95%

description

≥95%

reaction suitability

reaction type: Asymmetric synthesis, reagent type: ligand
reaction type: Hydrosilylations

reaction suitability

-

reaction suitability

reaction type: Asymmetric synthesis, reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

reaction suitability

-

assay

96%

assay

97%

assay

95%

assay

≥95%

form

solid

form

solid

form

solid

form

powder or crystals

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

-

mp

185-190 °C

mp

261-265 °C

mp

-

mp

226-228 °C

optical activity

[α]/D -97.0°, c = 0.5% in dichloromethane

optical activity

[α]20/D +98°, c = 1 in chloroform

optical activity

-

optical activity

-


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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