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190888

Poly[(2-ethyldimethylammonioethyl methacrylate ethyl sulfate)-co-(1-vinylpyrrolidone)]

average Mw <1,000,000 by GPC, 20 wt. % in H2O

Synonym(s):

Poly(1-vinylpyrrolidone-co-2-dimethylaminoethyl methacrylate), Polyquaternium D 11

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Pack SizeSKUAvailabilityPrice
250 g
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$264.00

About This Item

CAS Number:
UNSPSC Code:
12162002
NACRES:
NA.23
MDL number:

$264.00


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form

solid

Quality Level

mol wt

average Mw <1,000,000 by GPC

concentration

20 wt. % in H2O

density

1.05 g/mL at 25 °C

SMILES string

[S](=O)(=O)(OCC)OCC.N1(CCCC1=O)C=C.N(CCOC(=O)C(=C)C)(C)C

InChI

1S/C8H15NO2.C6H9NO.C4H10O4S/c1-7(2)8(10)11-6-5-9(3)4;1-2-7-5-3-4-6(7)8;1-3-7-9(5,6)8-4-2/h1,5-6H2,2-4H3;2H,1,3-5H2;3-4H2,1-2H3

InChI key

XXJPSODUGQZOHA-UHFFFAOYSA-N

General description

Poly[(2-ethyldimethylammonioethyl methacrylate ethyl sulfate)-co-(1-vinylpyrrolidone)] is a cationic polyelectrolyte that can be used as a reducing and protective agent to synthesize nanoparticles.

Preparation Note

Quaternized with diethyl sulfate

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This Item
657670474576181560
form

solid

form

solid

form

solid

form

powder

density

1.05 g/mL at 25 °C

density

-

density

1.3 g/mL at 25 °C (lit.)

density

1.09 g/mL at 25 °C (lit.)

mol wt

average Mw <1,000,000 by GPC

mol wt

-

mol wt

Mn 3,000-5,000 Da, average Mw 8.000-12,000 Da

mol wt

average Mw ~354,000 by GPC

concentration

20 wt. % in H2O

concentration

-

concentration

-

concentration

-

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

100


Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Articles

Self-assembled monolayers (SAMs) have diverse applications; article compares benefits of alkylthiolates on gold SAM systems.





Global Trade Item Number

SKUGTIN
190888-250G04061837850738

Questions

1–2 of 2 Questions  
  1. What is the ratio between the two monomers? (mass or mol ratio)

    1 answer
    1. Unfortunately, the ratio between the two monomers is not determined for this product on a lot-to-lot basis. However, historical data indicates a mixture of approximately 83 wt% 1-vinylpyrrolidinone and 17 wt% 2-dimethyl-aminoethyl methacrylate.

      Helpful?

  2. How many repeating units are there in this copolymer?

    1 answer
    1. Approximately 83% 1-vinylpyrrolidinone and approximately 17% 2-dimethyl-aminoethyl methacrylate. Since the average Mw of 190888 is less than 1,000,000, theoretically there should be 830,000 of 1-vinylpyrrolidinone and 170,000 of 2-dimethyl-aminoethyl methacrylate. The Mw of each 1-vinylpyrrolidinone and 2-dimethyl-aminoethyl methacrylate unit is 111.144 and 157.21, respectively. Therefore, the repeating unit can be calculated as 830,000/111.144 ≈ 7468 and 170,000/157.21 ≈ 1081, respectively.

      Helpful?

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