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Professor Abigail Doyle Professor Josep Cornella

The main focus of the Cornella research group is the development of rapid, practical and efficient methodologies for organic synthesis. In addition to efficiency and practicality, the group is highly interested in discovering new reactivity with the aim of unveiling novel transformations. More specifically, on the fundamental understanding and application of catalytic processes and the development of simple reagents. These two approaches have enormous potential and impact across the chemical sciences.

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Moser D, Duan Y, Wang F, Ma Y, O'Neill MJ, Cornella J.
Angew Chem Int Ed Engl. 2018 Aug 20;57(34):11035-11039. doi: 10.1002/anie.201806271. Epub 2018 Jul 20.
The functionalization of aminoheterocycles by using a pyrylium tetrafluoroborate reagent (Pyry-BF4 ) is presented. This reagent efficiently condenses with a great variety of heterocyclic amines and primes the C-N bond for nucleophilic aromatic substitution. More than 60 examples for the formation of C-O, C-N, C-S, or C-SO2 R bonds are disclosed herein...Read More