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Merck

208825

Copper(I) oxide

powder, ≤7 μm, 97%

Synonym(s):

Cuprous oxide

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25 G

$173.00

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$251.00

2 KG

$725.00

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About This Item

Linear Formula:
Cu2O
CAS Number:
Molecular Weight:
143.09
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
215-270-7
MDL number:
Assay:
97%
Form:
powder

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Product Name

Copper(I) oxide, powder, ≤7 μm, 97%

InChI key

BERDEBHAJNAUOM-UHFFFAOYSA-N

InChI

1S/2Cu.O

SMILES string

[Cu]O[Cu]

assay

97%

form

powder

contains

stabilizer

particle size

≤7 μm

density

6 g/mL at 25 °C (lit.)

Quality Level

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1 of 4

This Item
5662844508121.02766
form

powder

form

powder

form

powder

form

solid

assay

97%

assay

≥99.99% trace metals basis

assay

99.99% trace metals basis

assay

≥99.0% (complexometric)

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

300

density

6 g/mL at 25 °C (lit.)

density

6 g/mL at 25 °C (lit.)

density

-

density

6.48 g/cm3 at 25 °C

contains

stabilizer

contains

-

contains

-

contains

-

particle size

≤7 μm

particle size

-

particle size

-

particle size

≤160 μm (d95,laser diffraction)

Application

Copper(I) oxide can be used as a catalyst to synthesize:
  • Ynones via solvent-free Sonogashira reaction[1].
  • N-Heteroaryl derivatives via cross-coupling of nitrogen heterocycles with halopyridines[2].

General description

Copper(I)oxide is a weak base that can be used in nucleophilic substitution, decarboxylation, cyclocondensation, and 1,1-addition reactions. It can also be used to form carbenoid intermediates from diazo compounds and radicals from arenediazonium salts[3].

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Dmytro S Kozak et al.
Scientific reports, 6, 21178-21178 (2016-02-18)
Electrolytic processes are widely used to synthesize different nanomaterials and it does not depend on what kind of the method has been applied (wet-chemistry, sonochemistry, plasma chemistry, electrolysis and so on). Generally, the reactions in the electrolyte are considered to
Copper (I) Oxide-Mediated Cyclization of o-Haloaryl N-Tosylhydrazones: Efficient Synthesis of Indazoles.
Tang M, et al.
Advanced Synthesis & Catalysis (2016)
A highly efficient nano-sized Cu2O/SiO2 egg-shell catalyst for C?C coupling reactions
Kim S, et al.
Royal Society of Chemistry Advances, 8, 6200-6205 (2018)
Copper (I) Oxide
Tuckmantel W
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
Ligand-free Cu2O-catalyzed cross coupling of nitrogen heterocycles with iodopyridines
Teo Y, et al.
Tetrahedron, 69, 7279-7284 (2013)

Questions

  1. Is it a white powder ??

    1 answer
    1. Copper(I) Oxide presents as a red to brown powder. There is no white powder form available.

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