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  • Reinvestigation of structures of robustasides B and C, and isolation of (E)-2,5-dihydroxycinnamic acid esters of arbutin and glucose from the leaves of Grevillea robusta.

Reinvestigation of structures of robustasides B and C, and isolation of (E)-2,5-dihydroxycinnamic acid esters of arbutin and glucose from the leaves of Grevillea robusta.

Chemical & pharmaceutical bulletin (2012-10-06)
Yukiko Yamashita-Higuchi, Sachiko Sugimoto, Katsuyoshi Matsunami, Hideaki Otsuka
RESUMEN

From the leaves of Grevillea robusta, compounds whose NMR data were superimposable on those of robustasides B and C were isolated along with two new compounds, (E)-2,5-dihydroxycinnamic acid esters of arbutin and D-glucose, and two known compounds, robustaside A and (E)-2,5-dihydroxycinnamic acid. The structures of robustasides B and C were not arbutin caffeates, being revised to arbutin (E)-2,5-dihydroxycinnamic acid esters.

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Sigma-Aldrich
Arbutin, ≥98% (HPLC)
Supelco
Arbutin, analytical standard
Arbutin, European Pharmacopoeia (EP) Reference Standard