Formic hydrazide

Name: Formic hydrazide
Brand: ALDRICH

Synonym(s):

Formic acid hydrazide, Formylhydrazine

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About This Item

Linear Formula:

HCONHNH₂

CAS Number:

624-84-0

Molecular Weight:

60.06

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24850161

EC Number:

210-867-9

Beilstein/REAXYS Number:

635759

MDL number:

MFCD00007589

Key Documents

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Quality Level

100

mp

52-57 °C (lit.)

solubility

water: soluble 2.5%, clear, colorless

functional group

amine, hydrazine

SMILES string

[H]C(=O)NN

InChI

1S/CH4N2O/c2-3-1-4/h1H,2H2,(H,3,4)

InChI key

XZBIXDPGRMLSTC-UHFFFAOYSA-N

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Organic Building Blocks

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This Item	107425	130443	671460
Sigma-Aldrich 166375 Formic hydrazide	Sigma-Aldrich 107425 Nicotinic hydrazide	130443 2-Furoic hydrazide	Sigma-Aldrich 671460 Propanoic acid hydrazide
solubility water: soluble 2.5%, clear, colorless	solubility H₂O: soluble 50 mg/mL	solubility -	solubility -
Quality Level 100	Quality Level 100	Quality Level 100	Quality Level 100
mp 52-57 °C (lit.)	mp 159-161 °C (lit.)	mp 77-79 °C (lit.)	mp -
functional group amine	functional group amine, hydrazine	functional group amine, hydrazine	functional group amine, hydrazine

Application

Formic hydrazide was used in the synthesis of 1,2,4-triazole derivatives. It was also used in the synthesis of new anticancer agent, 6-N-formylamino-12,13-dihydro-1,11-dihydroxy-13-(β-D-glucopyranosyl)-5H-indolo[2,3-a]-pyrrolo[3,4-c]carbazole-5,7(6H)-dione.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

233.6 °F - closed cup

flash_point_c

112 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis of NB-506, a new anticancer agent.

Ohkubo M, et al.

Tetrahedron, 53(2), 585-592 (1997)

Thermo-Reversible Hybrid Gels Formed from the Combination of Isotactic Polystyrene and [Fe(II) (4-Octadecyl-1,2,4-Triazole)3(ClO4)2]n Metallo-Organic Polymer: Thermal and Viscoelastic Properties.

Coro Echeverría et al.

Polymers, 11(6) (2019-06-05)

Nano-sized one-dimensional metallo-organic polymers, characterized by the phenomenon of spin transition, are excellent candidates for advanced technological applications such as optical sensors, storage, and information processing devices. However, the main drawback of this type of polymers is their fragile mechanical

N-ethyl-N-formylhydrazine tumorigenesis in mice.

B Toth et al.

Carcinogenesis, 1(1), 61-65 (1980-01-01)

N-ethyl-N-formylhydrazine (EFH) was administered as a 0.02% solution in drinking water continuously for life to randomly bred Swiss mice, from 6 weeks of age. The treatment induced tumors of the lungs, blood vessels, liver, gall bladder and preputial glands. The

Traceless liquid-phase synthesis of 3-alkylamino-4, 5-disubstituted-1, 2, 4-triazoles on polyethylene glycol (PEG).

Zong Y-X, et al.

Tetrahedron Letters, 46(31), 5139-5141 (2005)

Global Trade Item Number

SKU	GTIN
P8791-100MG	04061832780771
166375-25G	04061831818901
166375-100G	04061831818895

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