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Merck

283622

Nickel(II) hydroxide

Synonym(s):

Nickel dihydroxide, Nickelous hydroxide

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250 G

CHF 114.00

1 KG

CHF 330.00

CHF 114.00


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About This Item

Linear Formula:
Ni(OH)2
CAS Number:
Molecular Weight:
92.71
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Form:
powder

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form

powder

reaction suitability

core: nickel

concentration

60.0-70.0% Ni (EDTA titration)

mp

230 °C (lit.)

density

4.1 g/mL (lit.)

application(s)

battery precursors
catalysts
material synthesis precursor

SMILES string

O[Ni]O

InChI

1S/Ni.2H2O/h;2*1H2/q+2;;/p-2

InChI key

BFDHFSHZJLFAMC-UHFFFAOYSA-L

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1 of 4

This Item
544183561142451193
form

powder

form

powder

form

powder

form

powder

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

200

grade

reference material

grade

-

grade

anhydrous

grade

anhydrous

mp

230 °C (lit.)

mp

-

mp

963 °C (lit.)

mp

-

density

4.1 g/mL (lit.)

density

-

density

5.098 g/mL at 25 °C (lit.)

density

3.55 g/mL at 25 °C (lit.)

concentration

60.0-70.0% Ni (EDTA titration)

concentration

-

concentration

-

concentration

-

Application

Nickel hydroxide was used as a reference material in a study where the influence of stacking faults on the electrochemical activity of Ni(OH)2 electrodes was studied.[1]

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Target Organs

Lungs

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Yong Wang et al.
Chemical communications (Cambridge, England), (41)(41), 5231-5233 (2005-10-18)
Ni(OH)2 hollow microspheres with beta-Ni(OH)2 nanosheets as the in situ formed building units were fabricated via a novel template-free approach in a strong alkaline solution of glycine, and can be converted into NiO hollow microspheres by a thermal decomposition process.
The effect of stacking faults on the electrochemical performance of nickel hydroxide electrodes.
Ramesh TN and Kamath PV
Mat. Res. Bul., 43(11), 2827-2832 (2008)
Yukina Takahashi et al.
Physical chemistry chemical physics : PCCP, 8(23), 2716-2719 (2006-06-10)
Oxidative energy generated by UV-irradiated TiO2 photocatalyst was stored in Ni(OH)2 that was 12.5-50 microm apart from the TiO2. It is likely that active oxygen species generated on TiO2 diffused into the gas phase and oxidized Ni(OH)2. Loading the TiO2
Jason G Parsons et al.
Environmental toxicology and chemistry, 29(5), 1146-1154 (2010-09-08)
Nanomaterials are of particular interest in environmental chemistry due to their unknown toxicity to living organisms. Reports indicate that nanoparticles (NPs) affect seed germination, but the uptake and biotransformation of metal nanoparticles is not well understood. The present study investigated
Tonje Skuland et al.
Basic & clinical pharmacology & toxicology, 126(4), 374-388 (2019-10-20)
Asbestos (Mg-hydrosilicate; chrysotile) is known to cause pleural diseases, pulmonary fibrosis and lung cancers, via mechanisms strongly depending on diameter-length ratio and possibly metal content. A critical question is whether synthetic hydrosilicate nanotubes (NTs) of short length possess little toxic

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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