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Merck

166375

Formic hydrazide

Synonym(s):

Formic acid hydrazide, Formylhydrazine

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25 G

CZK 1,650.00

100 G

CZK 5,490.00

CZK 1,650.00

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About This Item

Linear Formula:
HCONHNH2
CAS Number:
624-84-0
Molecular Weight:
60.06
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24850161
EC Number:
210-867-9
Beilstein/REAXYS Number:
635759
MDL number:
MFCD00007589

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InChI key

XZBIXDPGRMLSTC-UHFFFAOYSA-N

InChI

1S/CH4N2O/c2-3-1-4/h1H,2H2,(H,3,4)

SMILES string

[H]C(=O)NN

mp

52-57 °C (lit.)

solubility

water: soluble 2.5%, clear, colorless

functional group

amine
hydrazine

Quality Level

100

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This Item
107425130443671460
Formic hydrazide

Sigma-Aldrich

166375

Formic hydrazide

Nicotinic hydrazide 97%

Sigma-Aldrich

107425

Nicotinic hydrazide

2-Furoic hydrazide 98%

Sigma-Aldrich

130443

2-Furoic hydrazide

Propanoic acid hydrazide ≥90% (GC)

Sigma-Aldrich

671460

Propanoic acid hydrazide

solubility

water: soluble 2.5%, clear, colorless

solubility

H2O: soluble 50 mg/mL

solubility

-

solubility

-

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

52-57 °C (lit.)

mp

159-161 °C (lit.)

mp

77-79 °C (lit.)

mp

-

functional group

amine

functional group

amine, hydrazine

functional group

amine, hydrazine

functional group

amine, hydrazine

Application

Formic hydrazide was used in the synthesis of 1,2,4-triazole derivatives[1]. It was also used in the synthesis of new anticancer agent, 6-N-formylamino-12,13-dihydro-1,11-dihydroxy-13-(β-D-glucopyranosyl)-5H-indolo[2,3-a]-pyrrolo[3,4-c]carbazole-5,7(6H)-dione[2].

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

233.6 °F - closed cup

flash_point_c

112 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN2805
BCCN1603
BCCH0831
BCCK8391
STBJ6879

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Synthesis of NB-506, a new anticancer agent.
Ohkubo M, et al.
Tetrahedron, 53(2), 585-592 (1997)
B Toth et al.
Carcinogenesis, 1(1), 61-65 (1980-01-01)
N-ethyl-N-formylhydrazine (EFH) was administered as a 0.02% solution in drinking water continuously for life to randomly bred Swiss mice, from 6 weeks of age. The treatment induced tumors of the lungs, blood vessels, liver, gall bladder and preputial glands. The
Traceless liquid-phase synthesis of 3-alkylamino-4, 5-disubstituted-1, 2, 4-triazoles on polyethylene glycol (PEG).
Zong Y-X, et al.
Tetrahedron Letters, 46(31), 5139-5141 (2005)
Coro Echeverría et al.
Polymers, 11(6) (2019-06-05)
Nano-sized one-dimensional metallo-organic polymers, characterized by the phenomenon of spin transition, are excellent candidates for advanced technological applications such as optical sensors, storage, and information processing devices. However, the main drawback of this type of polymers is their fragile mechanical

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