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Solvent effect in reactions using Stryker's reagent.

The Journal of organic chemistry (2012-09-20)
Daiane Cristina Sass, Vladimir Constantino Gomes Heleno, Simone Cavalcante, Jader da Silva Barbosa, Ana Carolina Ferreira Soares, Mauricio Gomes Constantino
ABSTRACT

The solvent has a significant influence in the rate of reactions promoted by Stryker's reagent. The reactions performed in THF were, in most cases, faster than in toluene.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Tetrahydrofuran, anhydrous, ≥99.9%, inhibitor-free
Supelco
Tetrahydrofuran, Selectophore, ≥99.5%
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Tetrahydrofuran, analytical standard
Sigma-Aldrich
Tetrahydrofuran, contains 200-400 ppm BHT as inhibitor, ACS reagent, ≥99.0%
Sigma-Aldrich
Tetrahydrofuran, ACS reagent, ≥99.0%, contains 200-400 ppm BHT as inhibitor
Sigma-Aldrich
Tetrahydrofuran, inhibitor-free, suitable for HPLC, ≥99.9%