sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

GF44280974

Nickel, rod, 200mm, diameter 40mm, 99%

GF70332870

Nickel, rod, 100mm, diameter 3.3mm, 99.99+%

GF55890298

Nickel, foil, 10mm disks, thickness 0.05mm, as rolled, 100%

GF17475903

Nickel, rod, 200mm, diameter 6.35mm, 99%

GF66250256

Nickel, rod, 200mm, diameter 10.0mm, 99.99+%

GF68841535

Nickel, foil, 10mm disks, thickness 0.20mm, annealed, 99%

GF86311009

Nickel, foil, 10mm disks, thickness 0.1mm, annealed, 99%

GF95866824

Nickel, rod, 200mm, diameter 30mm, 99%

GF67821543

Nickel, rod, 500mm, diameter 20.0mm, 99%

GF49774034

Nickel, rod, 200mm, diameter 12.7mm, 99.98%

GF23820128

Nickel, foil, 10mm disks, thickness 0.3mm, as rolled, 100%

GF50593002

Nickel, rod, 100mm, diameter 9.5mm, 99%

GF90764220

Nickel, foil, 10mm disks, thickness 0.5mm, as rolled, 100%

GF32204775

Nickel, foil, 10mm disks, thickness 0.05mm, as rolled, 99.99+%

GF68355085

Nickel, rod, 200mm, diameter 1.5mm, 99.99+%

GF11598194

Nickel, rod, 100mm, diameter 12.7mm, 99.98%

GF23987605

Nickel, foil, 25mm disks, thickness 0.02mm, 99.9%

GF27610589

Nickel, tube, 200mm, outside diameter 3.6mm, inside diameter 3.5mm, wall thickness 0.05mm, hard, 99.5%

GF03591110

Nickel, foil, 1m coil, thickness 0.038mm, 99.9%

GF41132708

Nickel, tube, 100mm, outside diameter 3.25mm, inside diameter 3.05mm, wall thickness 0.1mm, hard, 99.5%

GF86286404

Nickel, foil, 15mm disks, thickness 0.05mm, as rolled, 100%

GF84917582

Nickel, tube, 200mm, outside diameter 0.65mm, inside diameter 0.384mm, wall thickness 0.133mm, as drawn, 99.5%

GF72676121

Nickel, tube, 200mm, outside diameter 1.8mm, inside diameter 1.6mm, wall thickness 0.1mm, hard, 99.5%

GF54839188

Nickel, tube, 100mm, outside diameter 2.5mm, inside diameter 2mm, wall thickness 0.25mm, hard, 99.5%