- Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.
Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.
Dalton transactions (Cambridge, England : 2003) (2007-11-07)
Isabelle Aillaud, Jacqueline Collin, Jérôme Hannedouche, Emmanuelle Schulz
PMID17985016
ABSTRACT
The catalysed enantioselective formation of carbon-nitrogen bonds by the hydroamination reaction is reviewed. All examples deal with substrates containing non-activated carbon-carbon multiple bonds which are transformed either via intramolecular or intermolecular reactions. Structurally different complexes already provided nitrogen containing compounds/heterocycles with high enantioselectivities.
MATERIALS
Product Number
Brand
Product Description
Sigma-Aldrich
Activated Charcoal Norit®, Norit® SX2, powder, from peat, multi-purpose activated charcoal, steam activated and acid washed
Carbon, rod, 100mm, diameter 13.0mm, graphite, 100%
Carbon, rod, 25mm, diameter 50mm, graphite, 99.95%
Carbon, foil, 8mm disks, thickness 0.2mm, flexible graphite, 99.8%
Carbon, foil, 50x50mm, thickness 0.2mm, pyrolytic graphite, 99.99%
Carbon, foil, 50x50mm, thickness 0.25mm, rigid graphite, fine grain size, 99.997%
Carbon, foil, 10x10mm, thickness 2.0mm, hOpg
Carbon, microleaf, 25x70mm, thinness 0.025μm, specific density 5μg/cm2, temporary glass support, 99.997%
Carbon, microleaf, 25x70mm, thinness 0.25μm, specific density 50μg/cm2, temporary glass support, 99.997%
Carbon, foil, 5x5mm, thickness 2.0mm, hOpg
Carbon, foil, 6mm disks, thickness 0.2mm, flexible graphite, 99.8%
Carbon, rod, 300mm, diameter 13.0mm, graphite, 100%
Carbon, rod, 100mm, diameter 2.0mm, graphite, 100%
Carbon, foil, not light tested, 100x100mm, thickness 0.075mm, flexible graphite, 99.8%
Carbon, foil, 50x50mm, thickness 0.35mm, flexible graphite, 99.8%
Carbon, foil, 5x10mm, thickness 2.0mm, hOpg
Carbon, rod, 150mm, diameter 25mm, graphite, 100%
Carbon, tube, graphite, 50mm, outside diameter 12.7mm, inside diameter 9.5mm, wall thickness 1.6mm, 99.95%
Carbon, foil, 10mm disks, thickness 0.2mm, flexible graphite, 99.8%
Carbon, foil, not light tested, 150x150mm, thickness 0.075mm, flexible graphite, 99.8%
Carbon, rod, 150mm, diameter 2.0mm, graphite, 100%