Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.

Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.

Dalton transactions (Cambridge, England : 2003) (2007-11-07)

Isabelle Aillaud, Jacqueline Collin, Jérôme Hannedouche, Emmanuelle Schulz

ABSTRACT

The catalysed enantioselective formation of carbon-nitrogen bonds by the hydroamination reaction is reviewed. All examples deal with substrates containing non-activated carbon-carbon multiple bonds which are transformed either via intramolecular or intermolecular reactions. Structurally different complexes already provided nitrogen containing compounds/heterocycles with high enantioselectivities.

MATERIALS

Product Number

Brand

Product Description

80485

Supelco

Activated charcoal, for the determination of AOX, 50-150 μm particle size

484164

Sigma-Aldrich

Carbon, glassy, spherical powder, 2-12 μm, 99.95% trace metals basis

C9157

Sigma-Aldrich

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05105

Supelco

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29238

Supelco

Activated Charcoal Norit^®, Norit^® RBAA-3, rod

05112

Millipore

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31616

Supelco

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Sigma-Aldrich

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242241

Sigma-Aldrich

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242276

Sigma-Aldrich

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242268

Sigma-Aldrich

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242233

Sigma-Aldrich

Activated charcoal, DARCO^®, 4-12 mesh particle size, granular

633100

Sigma-Aldrich

Carbon, nanopowder, <100 nm particle size (TEM)

GF91212511

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Carbon, foil, 300x300mm, thickness 0.2mm, flexible graphite, 99.8%

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Carbon, foil, 25x25mm, thickness 0.25mm, rigid graphite, fine grain size, 99.95%

GF15163297

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Carbon, foil, 150x150mm, thickness 0.125mm, rigid graphite, fine grain size, 99.95%

GF99536338

Carbon, foil, 500x500mm, thickness 0.2mm, flexible graphite, 99.8%

GF39402716

Carbon, tube, graphite, 150mm, outside diameter 6.35mm, inside diameter 3.15mm, wall thickness 1.6mm, 99.95%

GF95821195

Carbon, rod, 50mm, diameter 50mm, graphite, 99.95%

GF61271018

Carbon, foil, 50mm disks, thickness 0.2mm, flexible graphite, 99.8%

GF86694069

Carbon, foil, 50x50mm, thickness 0.25mm, rigid graphite, fine grain size, 99.997%

GF26117636

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GF42290939

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