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Merck

Ensiling of seaweed for a seaweed biofuel industry.

Bioresource technology (2015-08-09)
Christiane Herrmann, Jamie FitzGerald, Richard O'Shea, Ao Xia, Pádraig O'Kiely, Jerry D Murphy
ABSTRACT

Effective biogas production from seaweed necessitates harvest at times of peak quality of biomass and low-loss preservation for year-around supply. Ensiling of five seaweed species and storage up to 90days was investigated as a method to preserve the methane yield potential. Adequate acidification by natural lactic acid fermentation was difficult due to low rapidly fermentable carbohydrate contents, high buffering capacities and low initial numbers of lactic acid bacteria. Nevertheless, products of silage fermentation increased methane yields by up to 28% and compensated for volatile solid losses during ensiling. Preservation of the original methane yield potential was achieved for four of five seaweed species, provided that silage effluent is collected and utilised. 10-28% of the ensiled biomass was released as effluent with methane yields of 218-423LNkg(-1) VS. If further optimised, ensiling represents an effective method of preservation crucial for an efficient seaweed biofuel industry.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Lactic acid solution, ACS reagent, ≥85%
Sigma-Aldrich
Propionic acid, ≥99.5%, FCC, FG
Sigma-Aldrich
Heptanoic acid, 97%, FG
Sigma-Aldrich
Propionic acid, natural, 99%, FG
Sigma-Aldrich
Valeric acid, ≥99%
Sigma-Aldrich
Propionic acid, ACS reagent, ≥99.5%
Sigma-Aldrich
Heptanoic acid, natural, FG
Sigma-Aldrich
Methane-12C, 13C-depleted, 99.99 atom % 12C
Sigma-Aldrich
Heptanoic acid, 96%
Sigma-Aldrich
Valeric acid, ≥99%, FCC, FG
Sigma-Aldrich
DL-Lactic acid, 85 % (w/w), syrup
Sigma-Aldrich
Propionic acid, BioReagent, suitable for insect cell culture, ~98%
Sigma-Aldrich
Heptanoic acid, ≥99.0% (GC)
Sigma-Aldrich
Propionic acid, puriss. p.a., ≥99.5% (GC)
Carbon - Vitreous, foam, 150x150mm, thickness 2.5mm, bulk density 0.05g/cm3, porosity 96.5%
Carbon - Vitreous, rod, 200mm, diameter 5.0mm, glassy carbon
Carbon - Vitreous, foil, 10x10mm, thickness 4.0mm, glassy carbon
Carbon - Vitreous, rod, 100mm, diameter 1.0mm, glassy carbon
Carbon - Vitreous, rod, 50mm, diameter 1.0mm, glassy carbon
Carbon - Vitreous, foil, 100x100mm, thickness 6.0mm, glassy carbon
Carbon - Vitreous, rod, 100mm, diameter 3.0mm, glassy carbon
Carbon - Vitreous, foam, 300x300mm, thickness 20mm, bulk density 0.05g/cm3, porosity 96.5%
Carbon - Vitreous, rod, 200mm, diameter 3.0mm, glassy carbon
Carbon - Vitreous, tube, 100mm, outside diameter 10mm, inside diameter 3mm, wall thickness 3.5mm, glassy carbon
Carbon - Vitreous, foil, 25x25mm, thickness 4.0mm, glassy carbon
Carbon - Vitreous, foam, 150x150mm, thickness 3.2mm, bulk density 0.05g/cm3, porosity 96.5%
Carbon - Vitreous, tube, 50mm, outside diameter 10mm, inside diameter 3mm, wall thickness 3.5mm, glassy carbon
Carbon - Vitreous, foil, 50x50mm, thickness 1.0mm, glassy carbon
Carbon - Vitreous, foam, 150x150mm, 0.05g.cmué, porosity 96.5%, 24 pores/cm
Carbon - Vitreous, foil, 10x10mm, thickness 1.0mm, glassy carbon