- Short access to (+)-lupinine and (+)-epiquinamide via double hydroformylation.
Short access to (+)-lupinine and (+)-epiquinamide via double hydroformylation.
Organic letters (2009-12-30)
Etienne Airiau, Thomas Spangenberg, Nicolas Girard, Bernhard Breit, André Mann
PMID20038131
ZUSAMMENFASSUNG
Short and efficient access to (+)-lupinine and (+)-epiquinamide by means of an unprecedented double hydroformylation of a bis-homoallylic azide followed by a tandem catalytic hydrogenation/reductive bis-amination is reported.