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Merck

Directed epoxidation of cyclohexa-1,4-dienes-stereoselective formation of up to six contiguous stereogenic centres.

Organic & biomolecular chemistry (2008-11-14)
Michael Butters, Dirk J Beetstra, Mark C Elliott, Joseph Hill-Cousins, Benson M Kariuki
RESUMEN

Epoxidation/cyclisation of cyclohexa-1,4-dienes containing pendant hydroxyl groups provides stereocontrolled access to highly-functionalised reduced benzol[b]furan derivatives.

MATERIALES
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Sigma-Aldrich
1,4-Cyclohexadiene, 97%
Sigma-Aldrich
1,4-Cyclohexadiene, purum, ≥97.0% (GC)