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Organotin Reagents

A sample of our organotin compound portfolio featuring allyltriphenylstannane, dibutyltin maleate, and tributyltin chloride

Organotin reagents are pivotal in progressing organic synthesis in the quest for synthesizing highly complex natural compounds and creating new chemical structures and known bond formations.  Organotin compounds, also known as stannanes, have at least one tin-carbon bond and are frequently utilized synthons in palladium-catalyzed cross coupling reactions. Since the first report by Stille in 1977, numerous applications of organotin reagents have become commonplace in the formation of new carbon-carbon (C-C) bonds for the synthesis of natural products and other small molecules for drug discovery.   

Organotin chemistry continues to be an active field of research in organometallic chemistry and has a wide range of pharmacological, agrochemical, and polymerization applications. Our organotin reagents are used for the generation of Stille Coupling precursors to obtain more complex coupling partners and dehalogenation reactions to afford hydrocarbons in late-stage synthetic sequences. 

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Products

aliphatic functional groups (48)

heterocyclic - 1 ring (12)

aromatic hydrocarbons (8)

CHO containing functional groups (4)

CHN containing functional groups (1)

halogen functional groups (1)

primary alkanes (44)

secondary alkanes (44)

cycloalkanes (14)

phenyl (8)

monosubstituted alkenes (5)

alkynes (4)

Sigma-Aldrich (42)
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Dibutyltin dilaurate
291234

Dibutyltin dilaurate

95%

Tributyltin hydride
234788

Tributyltin hydride

contains 0.05% BHT as stabilizer, 97%

Tributyltin chloride
T50202

Tributyltin chloride

96%

Trimethyltin chloride
146498

Trimethyltin chloride

Dibutyltin(IV) oxide
183083

Dibutyltin(IV) oxide

98%

Bis(tributyltin)
251127

Bis(tributyltin)

95%

Tributyl(vinyl)tin
271438

Tributyl(vinyl)tin

97%

Tributyl(1-ethoxyvinyl)tin
275123

Tributyl(1-ethoxyvinyl)tin

97%

Dibutyltin dilaurate
8.20421

Dibutyltin dilaurate

for synthesis

Allyltributylstannane
271411

Allyltributylstannane

97%

2-(Tributylstannyl)thiophene
414492

2-(Tributylstannyl)thiophene

97%

Dibutyltin dichloride
205494

Dibutyltin dichloride

96%

Trimethyltin chloride solution
375195

Trimethyltin chloride solution

1.0 M in THF

2-(Tributylstannyl)pyridine
678333

2-(Tributylstannyl)pyridine

85%

Dimethyltin dichloride
288012

Dimethyltin dichloride

97%

Dibutyltin diacetate
290890

Dibutyltin diacetate

technical grade

Trimethyltin chloride solution
375187

Trimethyltin chloride solution

1.0 M in hexanes

Diphenyltin dichloride
229202

Diphenyltin dichloride

96%

Bis(tributylstannyl)acetylene
271403

Bis(tributylstannyl)acetylene

95%

Butyltin trichloride
201057

Butyltin trichloride

95%

You have viewed 1-20 of 88 results
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Our extensive portfolio of organotin compounds includes:

  • Organotin halides
  • Organotin hydrides
  • Organotin oxides and hydroxides
  • Hypercoordinated stannanes
  • Triorganotin salts

We also offer other organometallic reagents to facilitate cross-coupling reactions and the discovery of new bond-forming methodologies. To view these reagents, visit our Organolithium, Organozinc, Organoaluminum, and Organosilicon reagents pages.

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Organotin Reagents
Our offering organotin reagents and compounds are useful in the formation of known bond formations and the development of new technologies in organic synthesis.
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C–H functionalization is the reliable and predictable conversion of a C–H into a C–C, C–N, C–O, or C–X bond in a selective and controlled fashion.
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