sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

268259

Sigma-Aldrich

Nickel, foil, thickness 0.125 mm, ≥99.9%

357634

Sigma-Aldrich

Nickel, wire, diam. 0.25 mm, ≥99.9%

203904

Sigma-Aldrich

Nickel, powder, <150 μm, 99.99% trace metals basis

510033

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 2400, slurry, in H₂O, active catalyst

510068

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 3202, slurry, in H₂O, active catalyst

510041

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 4200, slurry, in H₂O, active catalyst

83440

Sigma-Aldrich

Activated Nickel Catalyst

267058

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.99% trace metals basis

267007

Sigma-Aldrich

Nickel, foil, thickness 0.25 mm, 99.995% trace metals basis

268283

Sigma-Aldrich

Nickel, powder, <1 μm, 99.8% trace metals basis

GF08322858

Nickel, foil, 2m coil, thickness 0.05mm, as rolled, 99.98%

GF17347282

Nickel, foil, not light tested, 148x300mm, thickness 0.003mm, 99.95%

GF86618672

Nickel, foil, 0.5m coil, thickness 0.125mm, annealed, 99.98%

GF62050036

Nickel, microfoil, disks, 10mm, thinness 0.5μm, specific density 438.8μg/cm², permanent mylar 3.5μm support, 99.99+%

GF48946988

Nickel, foil, 25mm disks, thickness 0.20mm, annealed, 99%

GF10173877

Nickel, foil, not light tested, 150x150mm, thickness 0.0125mm, annealed, 99%

GF37862129

Nickel, foil, 2m coil, thickness 0.025mm, 99.9%

GF64388885

Nickel, foil, 25mm disks, thickness 0.5mm, as rolled, 99.99+%

GF32263354

Nickel, foil, 25x25mm, thickness 0.25mm, as rolled, 99.99+%

GF00494883

Nickel, foil, 10m coil, thickness 0.20mm, coil width 1mm, annealed, 99%

GF86630283

Nickel, foil, 0.5m coil, thickness 0.125mm, as rolled, 99.99+%

GF36327652

Nickel, foil, 150x150mm, thickness 0.25mm, annealed, 99%

GF57351731

Nickel, microfoil, disks, 10mm, thinness 1.0μm, specific density 895.8μg/cm², permanent mylar 3.5μm support, 99.99+%

GF33964566

Nickel, foil, not light tested, 100x100mm, thickness 0.007mm, 99.95%

GF97678995

Nickel, wire reel, 10m, diameter 0.25mm, as drawn, 99.99+%

GF87457067

Nickel, foil, 2m coil, thickness 0.0075mm, 99.9%

GF84295840

Nickel, foil, 10mm disks, thickness 0.025mm, annealed, 99%

GF97375832

Nickel, foil, 25x25mm, thickness 1.0mm, as rolled, 99.99+%

GF65651564

Nickel, foil, 10m coil, thickness 0.3mm, coil width 1mm, annealed, 99%

GF17533997

Nickel, wire reel, 100m, diameter 0.5mm, annealed, 99%