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Merck

345245

Phosphoric acid

greener alternative

85 wt. % in H2O, 99.99% trace metals basis

Phosphoric acid
1 of 2 reviewers received a sample product or took part in a promotion

Synonym(s):

Orthophosphoric acid

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100 ML

€192.00

500 ML

€675.00

€192.00


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About This Item

Linear Formula:
H3PO4
CAS Number:
Molecular Weight:
98.00
Beilstein:
1921286
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

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vapor density

3.4 (vs air)

vapor pressure

2.2 mmHg ( 20 °C)
5 mmHg ( 25 °C)

Assay

99.99% trace metals basis

form

liquid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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concentration

85 wt. % in H2O

bp

158 °C (lit.)

mp

~40 °C (lit.)

density

1.685 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

greener alternative category

SMILES string

OP(O)(O)=O

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)

InChI key

NBIIXXVUZAFLBC-UHFFFAOYSA-N

Gene Information

human ... SRC(6714)

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This Item
452289466123P5811
Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

assay

99.99% trace metals basis

assay

≥99.999% trace metals basis

assay

≥99.999% trace metals basis

assay

85%

form

liquid

form

liquid

form

crystalline

form

liquid

application(s)

battery manufacturing

application(s)

battery manufacturing

application(s)

-

application(s)

-

bp

158 °C (lit.)

bp

158 °C (lit.)

bp

158 °C (lit.)

bp

158 °C (lit.)

mp

~40 °C (lit.)

mp

~40 °C (lit.)

mp

~40 °C (lit.), 41-44 °C

mp

~40 °C (lit.)

General description

In aqueous solutions, phosphoric acid behaves as a triprotic acid. The triprotic acid has three ionizable hydrogen atoms, which are lost sequentially.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Industrially, phosphoric acid may be used in pharmaceuticals, water softeners.
Phosphoric acid (85 wt. % in H2O) can be used for a variety of applications, such as:
  • a medium for corrosion inhibition on mild steel[1]
  • an activating agent in the preparation of activated carbon[2]
  • enhancement of electrochemical performance for energy devices[3]
  • in the development of polymeric membranes for proton exchange membrane based fuel cells[4][5][6]

Phosphoric acid has been used as an acid solution for pH adjustment of the fermentation broth in a protocol for the acetone-butanol-ethanol (ABE) fermentation of sugars in a bioreactor.[7]

Packaging

Packaged in clear glass bottles

Other Notes

Concentrated phosphoric acid is approx. 85% H3PO4 (aqueous).

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Production of an acetone-butanol-ethanol mixture from Clostridium acetobutylicum and its conversion to high-value biofuels.
Sreekumar S, et al.
Nature Protocols, 10(3), 528-537 (2015)
Proton conductivity of phosphoric acid doped polybenzimidazole and its composites with inorganic proton conductors
He R, et al.
Journal of Membrane Science , 226(1-2), 169-184 (2003)
Preparation and characterization of activated carbon from bamboo by microwave-induced phosphoric acid activation
Liu Q, et al.
Industrial Crops and Products, 31(2), 233-238 (2010)
Physicochemical properties of phosphoric acid doped polybenzimidazole membranes for fuel cells
He R, et al.
Journal of Membrane Science , 277(1-2), 38-45 (2006)
Proton-conducting membranes based on benzimidazole polymers for high-temperature PEM fuel cells. A chemical quest
Asensio JA, et al.
Chemical Society Reviews, 39(8), 3210-3239 (2010)

Articles

Acid and base chart lists the strength of acids and bases (strongest to weakest) in order. Simple to use laboratory reference chart for scientists, researchers and lab technicians.

Related Content

Batteries, fuel cells, and supercapacitors rely on electrochemical energy production. Understand their operation and electron/ion transport separation.

Batterie, celle a combustibile e supercondensatori sfruttano reazioni elettrochimiche per produrre o immagazzinare energia. Scoprite come funzionano e il concetto di trasporto separato di elettroni e ioni.

Questions

1–5 of 5 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How to dilute 85% phosphoric acid?

    1 answer
    1. This product is an 85% solution in water. Further dilutions may also be made in water.

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  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  4. Does "wt. %" mean weight/volume or weight/weight? I.e. in 100mL of 85% "wt. %" phosphoric acid with a density of 1.685 g/mL (168.5 g), are there 85 grams of phosphoric acid or 143.225 grams of phosphoric acid?

    1 answer
    1. "wt%" means weight/weight %. In 100 mL of 85 wt% phosphoric acid with a density of 1.685 g/mL, there are 1.685 x 100 x 0.85 = 143.225 g of phosphoric acid.

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  5. What are the molarity and normality of an 85% w/w solution of phosphoric acid?

    1 answer
    1. The molarity of an 85% w/w solution of phosphoric acid is 14.615 M. Each mole of H3PO4 yields 3 moles of H+ ions, so the normality can be calculated by multiplying the molarity by the n-factor. Thus, the normality is 43.85 N.

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