931950

Sodium perchlorate

≥99.9% trace metals basis

• Synonym(s): Sodium Perchlorate, Hyperchloric acid sodium salt
• Empirical Formula (Hill Notation): ClNaO₄
• CAS Number: 7601-89-0
• Molecular Weight: 122.44
• MDL number: MFCD00003480
• UNSPSC Code: 12352302
• NACRES: NA.23
• Assay: ≥99.9% trace metals basis
• Grade: anhydrous
• Form: powder
• Solubility: H₂O: 209 g/dL at 15 °C

Properties

• grade: anhydrous
• Quality Level: 100
• Assay: ≥99.9% trace metals basis
• form: powder
• reaction suitability: core: sodium
• impurities: ≤1000 ppm (trace metals analysis)
• pH: 6.0-8.0 (25 °C, 5%, aq.sol.)
• mp: 482 °C
• solubility: H₂O: 209 g/dL at 15 °C
• anion traces: chloride (Cl^-): ≤30 ppm; sulfate (SO₄^2-): ≤20 ppm
• cation traces: Fe: ≤5 ppm; K: ≤500 ppm
• SMILES string: [Na+].[Cl](=O)(=O)(=O)[O-]
• InChI: 1S/ClHO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
• InChI key: BAZAXWOYCMUHIX-UHFFFAOYSA-M

Description

General description

Anhydrous sodium perchlorate is a white crystalline solid. It is hygroscopic and absorbs water to form its monohydrate. Anhydrous sodium perchlorate is highly soluble in water, and soluble in a range of polar organic solvents such as methanol, ethanol, acetone, carbonates (including ethylene carbonate, dimethyl carbonate, propylene carbonate, and diethyl carbonate), and ethers (including dimethoxyethane, tetrahydrofuran, and triethylene glycol dimethyl ether). It is insoluble in benzene, chloroform, and toluene.

Application

The major application of anhydrous sodium perchlorate is as an electrolyte in sodium-ion batteries. It is popular because of its solubility in ethers and carbonates, its wide electrochemical stability window (e.g. from 0 to 5 V vs Na+/Na in propylene carbonate, triglyme, or diethylcarbonate)[1], and its compatibility with a wide range of materials. It has been used in batteries with hard-carbon anodes[2], mesoporous carbon anodes[3], sodium cobalt oxide cathodes (Na_xCoO₂)[4], sodium vanadium oxide cathodes (Na_xVO₂)[5], titanium dioxide cathodes[6], and emerging materials like high-entropy layered oxide cathodes[7].

Packaging

10 g in glass bottle
25 g in glass bottle

Safety Information

• Pictograms: GHS03,GHS08,GHS07
• Signal Word: Danger
• Hazard Statements: H271,H302,H319,H373
• Precautionary Statements: P210 - P220 - P260 - P301 + P312 - P305 + P351 + P338 - P314
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 1 - STOT RE 2
• Target Organs: Thyroid
• Storage Class Code: 5.1A - Strongly oxidizing hazardous materials
• WGK: WGK 1