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Merck

705551

Hydrogen chloride solution

3 M in cyclopentyl methyl ether (CPME)

Synonym(s):

Hydrochloric acid in CPME

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About This Item

Empirical Formula (Hill Notation):
HCl
CAS Number:
7647-01-0
Molecular Weight:
36.46
NACRES:
NA.22
PubChem Substance ID:
329762569
UNSPSC Code:
12352301
MDL number:
MFCD00011324

Key Documents

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Product Name

Hydrogen chloride solution, 3 M in cyclopentyl methyl ether (CPME)

InChI

1S/ClH/h1H

SMILES string

Cl

InChI key

VEXZGXHMUGYJMC-UHFFFAOYSA-N

form

liquid

concentration

2.85-3.30 M (silver nitrate titration)
3 M in cyclopentyl methyl ether (CPME)

bp

106 °C

density

0.895 g/mL at 25 °C

storage temp.

2-8°C

Quality Level

100

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Application

Hydrogen chloride solution can be used in the Pinner synthesis of imidate hydrochlorides, which involves acid-catalyzed condensation of a nitrile and an alcohol under anhydrous conditions.

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

50.0 °F

flash_point_c

10 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
SHBT1084
SHBS7505
SHBS7101
SHBS5036
SHBS4660

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The Chemistry of Imidates.
Roger R and Neilson D G
Chemical Reviews, 61(2), 179-211 (1961)
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Davide R Ceratti et al.
Advanced materials (Deerfield Beach, Fla.), 27(34), 4958-4962 (2015-07-23)
A new, simple bi-phasic dip-coating method is developed. This method is considered as a great improvement of the technique for research, development and production, since expensive, rare, harmful, or time-evolving solutions can now be easily deposited on large surfaces and
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Neuropsychopharmacology : official publication of the American College of Neuropsychopharmacology, 40(4), 1005-1015 (2014-10-21)
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