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Merck

87860

Tetramethylhydrazine

≥97.0%

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About This Item

Linear Formula:
(CH3)2NN(CH3)2
CAS Number:
Molecular Weight:
88.15
EC Number:
229-119-8
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1731483
MDL number:
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Product Name

Tetramethylhydrazine, ≥97.0%

InChI key

DHBZRQXIRAEMRO-UHFFFAOYSA-N

InChI

1S/C4H12N2/c1-5(2)6(3)4/h1-4H3

SMILES string

CN(C)N(C)C

assay

≥97.0%

form

liquid

impurities

≤2% water

refractive index

n20/D 1.404

density

0.777 g/mL at 20 °C (lit.)

Quality Level

pictograms

Flame

signalword

Warning

hcodes

Hazard Classifications

Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

80.6 °F - closed cup

flash_point_c

27 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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B Kalyanaraman et al.
Carcinogenesis, 4(10), 1341-1343 (1983-10-01)
Prostaglandin endoperoxide synthase catalyzed the oxidation of tetramethylhydrazine to the tetramethylhydrazine radical cation, as detected by electron spin resonance spectroscopy. Oxidation of tetramethylhydrazine by prostaglandin endoperoxide synthase also resulted in the N-demethylation of tetramethylhydrazine leading to the formation of formaldehyde.
P A Craven et al.
Biochemical pharmacology, 34(17), 3101-3106 (1985-09-01)
A fatty acid stimulated, NADPH-independent pathway for the N-demethylation of 1,1-dimethylhydrazine (1,1-DMH) with the generation of HCHO was demonstrated in 10,000 g soluble fractions of colonic mucosal homogenates. Tetramethylhydrazine and, to a lesser extent, aminopyrine, but not 1,2-DMH or methylhydrazine
An electron spin resonance study of the novel radical cation produced during the horseradish peroxidase-catalyzed oxidation of tetramethylhydrazine.
B Kalyanaraman et al.
Biochemical and biophysical research communications, 105(1), 217-224 (1982-03-15)

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