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About This Item
Linear Formula:
C16H18(C29H40)n
CAS Number:
MDL number:
NACRES:
NA.23
UNSPSC Code:
12352103
Product Name
Poly(9,9-dioctylfluorenyl-2,7-diyl) end capped with dimethylphenyl, Mw 50,000-150,000 by GPC
description
Emissive Layer
PL: 421 nm in THF
mol wt
Mw 50,000-150,000 by GPC
greener alternative product characteristics
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
band gap
2.5 eV
solubility
THF: soluble
chlorobenzene: soluble
chloroform: soluble
dichlorobenzene: soluble
λmax
368 nm in THF
orbital energy
HOMO -5.3 eV
LUMO -2.8 eV
greener alternative category
Quality Level
Application
Highly emissive poly(9,9-dioctylfluorenyl-2, 7-diyl) end capped with dimethylphenyl (PFO-DMP) is a conjugated polymer with white light emision, remarkable thermal stability and high photo- and electroluminescence efficiency. PFO-DMP was successfully demonstrated in textile digital printing for organic light emission devices (OLEDs) , as well as in high voltage composite separator in Lithium batteries at high rates and low temperatures.
PFO-DMPP can be used as an active material in the fabrication of LEDs. The modification with dimethylphenyl end-capping groups can enhance the charge injection and transport characteristics, leading to improved device efficiency and stability. It can be used in applications in OPV devices, particularly as a donor material. The end-capping with dimethylphenyl groups can modify the energy levels and molecular packing, impacting the optical and electrical properties. PFO-DMPP can be utilized as an active layer in organic thin-film transistors (OTFTs) due to its improved charge transport characteristics. The end-capping groups help to enhance the carrier mobility and improve the performance of the transistors. This modification can influence the power conversion efficiency of the OPV cells.
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Hole transport organic materials allow perfect energy level alignment with the absorber layer and therefore efficient charge collection, are prone to degradation in ambient conditions.Click here for more information.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Overcharge Protection for 4 V Lithium Batteries at High Rates and Low Temperatures.
Chen G, et al.
Journal of the Electrochemical Society, 157, A735-A740 (2010)
Efficient white light emission in conjugated polymer homojunctions.
Ho G K, et al.
Applied Physics Letters, 85, 4576-4578 (2004)
Characterization of digital textile printing and polymer blend (PFO-DMP:P3HT) for application in manufacture of organic diodes emitting white light - WOLEDS.
Da Silva M A T, et al.
Optical Materials, 62, 119-131 (2016)
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