This product has not been validated for compatibility with LC-MS applications.
78314
Ammonium formate solution
BioUltra, 10 M in H2O
Synonym(s):
Ammonium salt of formic acid, ammonium formate
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About This Item
Linear Formula:
HCOONH4
CAS Number:
Molecular Weight:
63.06
UNSPSC Code:
12352106
eCl@ss:
39021903
PubChem Substance ID:
NACRES:
NA.25
MDL number:
Grade:
reagent grade
Form:
liquid
Solubility:
H2O: 10 M at 20 °C, clear, colorless
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Product Name
Ammonium formate solution, BioUltra, 10 M in H2O
SMILES string
[NH4+].[O-]C=O
InChI key
VZTDIZULWFCMLS-UHFFFAOYSA-N
InChI
1S/CH2O2.H3N/c2-1-3;/h1H,(H,2,3);1H3
grade
reagent grade
product line
BioUltra
form
liquid
concentration
10 M in H2O
impurities
insoluble matter, passes filter test
pH
6.0-8.0 (25 °C, 10 M in H2O)
solubility
H2O: 10 M at 20 °C, clear, colorless
anion traces
chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg
cation traces
Al: ≤1 mg/kg
As: ≤0.1 mg/kg
Ba: ≤1 mg/kg
Bi: ≤1 mg/kg
Ca: ≤5 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤1 mg/kg
K: ≤20 mg/kg
Li: ≤1 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Mo: ≤1 mg/kg
Na: ≤20 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Sr: ≤1 mg/kg
Zn: ≤1 mg/kg
λ
10 M in H2O
UV absorption
λ: 260 nm Amax: 0.05
λ: 280 nm Amax: 0.04
Quality Level
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This Item | 70221 | 798568 | 516961 |
|---|---|---|---|
| form liquid | form crystals | form crystals | form crystalline |
| solubility H2O: 10 M at 20 °C, clear, colorless | solubility H2O: 1 M at 20 °C, clear, colorless | solubility - | solubility - |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 200 |
| cation traces Al: ≤1 mg/kg, Ba: ≤1 mg/kg, Ca: ≤5 mg/kg, Co: ≤1 mg/kg, Cu: ≤1 mg/kg, K: ≤20 mg/kg, Mg: ≤1 mg/kg, Mo: ≤1 mg/kg, Ni: ≤1 mg/kg, Sr: ≤1 mg/kg, As: ≤0.1 mg/kg, Cd: ≤1 mg/kg, Fe: ≤1 mg/kg, Mn: ≤1 mg/kg, Pb: ≤1 mg/kg, Bi: ≤1 mg/kg, Li: ≤1 mg/kg, Zn: ≤1 mg/kg, Na: ≤20 mg/kg, Cr: ≤1 mg/kg | cation traces Al: ≤1 mg/kg, As: ≤0.1 mg/kg, Ba: ≤1 mg/kg, Bi: ≤1 mg/kg, Ca: ≤5 mg/kg, Cd: ≤1 mg/kg, Co: ≤1 mg/kg, Cr: ≤1 mg/kg, Cu: ≤1 mg/kg, Fe: ≤1 mg/kg, K: ≤5 mg/kg, Li: ≤1 mg/kg, Mg: ≤1 mg/kg, Mn: ≤1 mg/kg, Mo: ≤1 mg/kg, Na: ≤5 mg/kg, Ni: ≤1 mg/kg, Pb: ≤1 mg/kg, Sr: ≤1 mg/kg, Zn: ≤1 mg/kg | cation traces - | cation traces - |
| anion traces chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤50 mg/kg | anion traces chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤50 mg/kg | anion traces - | anion traces - |
| impurities insoluble matter, passes filter test | impurities insoluble matter, passes filter test, <2% water | impurities - | impurities ≤50.0 ppm Trace Metal Analysis |
Application
Ammonium formate has been used as a constituent in pre-mixed eluents for forming gradient during quantification of diuron by liquid chromatography-mass spectrometry (LC-MS).[1]
General description
Ammonium formate is readily available, stable and nontoxic in nature. It can be used in conjugation with palladium on carbon (Pd-C) or Raney-nickel catalysts.[2]
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
Storage Class
10 - Combustible liquids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Evaluation of phototrophic stream biofilms under stress: comparing traditional and novel ecotoxicological endpoints after exposure to diuron
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A general procedure for mild and rapid reduction of aliphatic and aromatic nitro compounds using ammonium formate as a catalytic hydrogen transfer agent.
Ram S and Ehrenkaufer RE.
Tetrahedron Letters, 25(32), 3415-3418 (1984)
Anne M Filppula et al.
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Is it compatible with LC-MS applications for trace analysis?
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdfHelpful?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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