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Tris(pentafluorophenyl)borane

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Alternative plus écologique

95%

Synonyme(s) :

Perfluorotriphenylboron

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1 g
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301,00 $
5 g
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1 030,00 $
100 g
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A propos de cet article

Formule linéaire :
(C6F5)3B
Numéro CAS:
Poids moléculaire :
511.98
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:

301,00 $


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Quality Segment

assay

95%

form

powder

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

mp

126-131 °C (lit.)

greener alternative category

SMILES string

Fc1c(F)c(F)c(B(c2c(F)c(F)c(F)c(F)c2F)c3c(F)c(F)c(F)c(F)c3F)c(F)c1F

InChI

1S/C18BF15/c20-4-1(5(21)11(27)16(32)10(4)26)19(2-6(22)12(28)17(33)13(29)7(2)23)3-8(24)14(30)18(34)15(31)9(3)25

InChI key

OBAJXDYVZBHCGT-UHFFFAOYSA-N

General description

Tris(pentafluorophenyl)borane is a highly fluorinated, boron-based Lewis acid significantly stronger than its inorganic counterpart, BF₃. Unlike the pentafluorides of heavier group 15 elements, B(C₆F₅)₃ exhibits no oxidizing properties. Its pronounced electrophilicity and thermal stability make it a versatile reagent, capable of forming stable adducts with neutral and weak Lewis bases, as well as accepting anionic ligands from metal complexes. These attributes render B(C₆F₅)₃ highly valuable in organometallic catalysis, doping of organic semiconductors, and both solution-phase and vapor-phase material fabrication, including thin-film deposition.
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Application

Tris(pentafluorophenyl)borane can be used as:

  • A surface passivation material to enhance the performance and stability of perovskite solar cells.
  • A p-type dopant and a Lewis acid receptor in poly(3-hexylthiophene) (P3HT)-based organic field-effect transistors (OFETs) for environmental ammonia monitoring.
  • A Lewis acid catalyst in the synthesis of advanced siloxane materials via Piers–Rubinsztajn reaction.
  • A catalyst in the cyclopropanation of styrenes with aryldiazoacetates to synthesize cyclopropane derivatives under mild conditions.
  • A versatile reagent widely used in the preparation of d0 arene and other organometallic complexes, useful as polymerization catalysts.
  • Used with tri-tert-butylphosphine (570958) to study the heterolytic cleavage of dihydrogen at room temperature and one atmosphere pressure.

Features and Benefits

A versatile reagent widely used in the preparation of d0 arene and other organometallic complexes useful as polymerization catalysts.

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230367419508307629
description

95%

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≥99.99%

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ReagentPlus®, ≥99%

description

95%

form

powder

form

liquid

form

-

form

solid

assay

95%

assay

≥99.99%

assay

≥99%

assay

95%

mp

126-131 °C (lit.)

mp

−46 °C (lit.)

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−46 °C (lit.)

mp

-

greener alternative product characteristics

Catalysis
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greener alternative product characteristics

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sustainability

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Quality Level

100

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200

Quality Level

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Quality Level

100


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signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Classe de stockage

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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