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E50604

Ethyltriphenylphosphonium bromide

99%

Synonym(s):

TEP

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Size/SKUAvailabilityPrice
25 g
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$50.10
$37.57
100 g
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$146.00

About This Item

Linear Formula:
[(C6H5)3P+C2H5]Br-
CAS Number:
Molecular Weight:
371.25
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-223-3
Beilstein/REAXYS Number:
3599630
MDL number:
Assay:
99%
Form:
crystalline

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Quality Segment

assay

99%

form

crystalline

reaction suitability

core: phosphonium, reaction type: C-C Bond Formation, reaction type: phase-transfer

mp

203-205 °C (lit.)

SMILES string

[Br-].CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C20H20P.BrH/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20;/h3-17H,2H2,1H3;1H/q+1;/p-1

InChI key

JHYNXXDQQHTCHJ-UHFFFAOYSA-M

Application

Reactant for synthesis of:
  • D-amino acids from L-cysteine-derived thiazolidines
  • Leiodolide A via aldol reactions and Horner-Wadsworth-Emmons olefination
  • Cycloalkanoindolines via diastereoselective intramolecular inimo-ene reactions
  • WXYZA′ domain of maitotoxin using the coupling of key building blocks

Reactant for:
  • Solid-state metathesis polycondensation to form alkyl-dipropenylthiophene monomers
  • Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization / lactonization cyclization reactions for synthesis of an ABC ring system

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This Item
130079A36603389471
description

99%

description

98%

description

99%

description

95%

assay

99%

assay

98%

assay

99%

assay

95%

reaction suitability

reaction type: C-C Bond Formation, core: phosphonium

reaction suitability

core: phosphonium, reaction type: C-C Bond Formation

reaction suitability

core: phosphonium, reaction type: C-C Bond Formation

reaction suitability

core: phosphonium, reaction type: C-C Bond Formation

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

mp

203-205 °C (lit.)

mp

230-234 °C (lit.)

mp

222-225 °C (lit.)

mp

164-168 °C (lit.)

form

crystalline

form

powder

form

powder

form

powder


Signal Word

Danger

Flash Point (°F)

401.0 °F

Flash Point (°C)

205 °C

PPE (personal protective equipment)

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects



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