C19686

2-Chlor-acetophenon

Name: 2-Chlor-acetophenon
Brand: ALDRICH

98%

Synonym(e):

ω-Chloracetophenon, Phenacylchlorid

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Lineare Formel:

C₆H₅COCH₂Cl

CAS-Nummer:

532-27-4

Molekulargewicht:

154.59

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24892454

EC Number:

208-531-1

Beilstein/REAXYS Number:

507950

MDL number:

MFCD00000933

Assay:

98%

Form:

crystals

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Produktname

2-Chlor-acetophenon, 98%

InChI key

IMACFCSSMIZSPP-UHFFFAOYSA-N

InChI

1S/C8H7ClO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2

SMILES string

ClCC(=O)c1ccccc1

assay

98%

form

crystals

bp

244-245 °C (lit.)

mp

54-56 °C (lit.)

density

1.324 g/mL at 25 °C (lit.)

Quality Level

200

Gene Information

human ... PTPN6(5777)

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Dieser Artikel	77460	115835	101273
Sigma-Aldrich C19686 2-Chloroacetophenone	Sigma-Aldrich 77460 2-Chloroacetophenone	Sigma-Aldrich 115835 2-Bromoacetophenone	Sigma-Aldrich 101273 2-Bromo-4′-chloroacetophenone
assay 98%	assay ≥98.0% (GC)	assay 98%	assay 98%
Quality Level 200	Quality Level 200	Quality Level 100	Quality Level 100
bp 244-245 °C (lit.)	bp 244-245 °C (lit.)	bp 135 °C/18 mmHg (lit.)	bp -
mp 54-56 °C (lit.)	mp 53-56 °C, 54-56 °C (lit.)	mp 48-51 °C (lit.)	mp 93-96 °C (lit.)
density 1.324 g/mL at 25 °C (lit.)	density 1.324 g/mL at 25 °C (lit.)	density -	density -
form crystals	form crystals	form solid	form solid

pictograms

GHS06,GHS08,GHS05

signalword

Danger

hcodes

H300,H311 + H331,H315,H318,H334,H335

pcodes

P261 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Lagerklasse

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Thermal decomposition studies of riot control agent ω-chloroacetophenone (CN) by pyrolysis-gas chromatography-mass spectrometry.

Anil K Nigam et al.

Journal of hazardous materials, 184(1-3), 506-514 (2010-09-17)

Pyrolysis-GC/MS system with on-line micro-furnace was used to make rapid evaluation of ω-chloroacetophenone (CN) decomposition under inert thermal atmospheres. The volatile products evolved during pyrolysis were analyzed by thermal gravimetric analysis (TGA) and Py-GC/MS to obtain specific thermogram and pyrogram.

Bioreduction of alpha-chloroacetophenone by whole cells of marine fungi.

Lenilson C Rocha et al.

Biotechnology letters, 31(10), 1559-1563 (2009-06-06)

The asymmetric reduction of 2-chloro-1-phenylethanone (1) by seven strains of marine fungi was evaluated and afforded (S)-(-)-2-chloro-1-phenylethanol with, in the best case, an enantiomeric excess of 50% and an isolated yield of 60%. The ability of marine fungi to catalyse

2-Pyridinealdoxime, a new ligand for a Pd-precatalyst: application in solid-phase-assisted Suzuki-Miyaura reaction.

Wladimir Solodenko et al.

Molecular diversity, 9(4), 333-339 (2005-11-29)

The preparation of a new palladium(II) complex with a 2-pyridinealdoxime ligand and its use as a Pd(0) precatalyst in the cross-coupling Suzuki-Miyaura reaction is described. Several concepts for the immobilization of this catalytic system are presented and compared in order

An evaluation of the relative potential public health concern for the self-defense spray active ingredients oleoresin capsicum, o-chlorobenzylidene malononitrile, and 2-chloroacetophenone.

Gregg M Recer et al.

Regulatory toxicology and pharmacology : RTP, 36(1), 1-11 (2002-10-18)

In 1996, the New York State Department of Health was charged by the State Legislature to develop regulations regarding the types of self-defense spray devices which could lawfully be purchased, possessed, and used in New York State. Prior to this

Isolation of a Bacillus strain producing ketone reductase with high substrate tolerance.

Yan Xie et al.

Bioresource technology, 101(3), 1054-1059 (2009-09-22)

Target reaction-oriented screening from soil samples yielded a ketone reductase-producing Bacillus sp., strain ECU0013, which exhibits excellent stereoselectivity, high substrate tolerance and is capable of regenerating the required cofactor with glucose as a co-substrate. Whole-cells catalyzed the asymmetric reduction of

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